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710            APPENDIX C  ■  Safety Data Sheets





               ■    Chemical  Abstracts  Service  (CAS)  number  an    other                                               an   cleanup practices to prevent or minimize exposure to
                    unique i  entif ers                                                                                    people, properties, or the environment. It may also inclu  e


               ■    Impurities an   stabilizing a    itives, which are themselves                                          recommen  ations    istinguishing  between  responses   or
                    classif e   an   which contribute to the classif cation o  the                                         large an   small spills where the spill volume has a signif cant

                    chemical                                                                                               impact on the hazar  . T e require   in ormation may consist

                                                                                                                           o  recommen  ations  or
                    Mixtures



               ■    Same in ormation require    or substances                                                              ■    Use o  personal precautions (such as removal o  ignition
                                                                                                                                sources or provi  ing su  cient ventilation) an   protective
               ■    T e chemical name an   concentration (i.e., exact percent-                                                  equipment to prevent the contamination o  skin, eyes, an
                    age) o  all ingre  ients which are classif e   as health haz-                                               clothing

                    ar  s an   are                                                                                              Emergency proce  ures, inclu  ing instructions  or evacu-


                    ●    Present above their cut-o  /concentration limits or                                               ■    ations, consulting experts when nee  e  , an   appropriate

                    ●    Present a health risk below the cut-o  /concentration                                                  protective clothing
                         limits                                                                                                 Metho  s an   materials use    or containment (e.g., cover-


               ■    T e concentration (exact percentages) o  each ingre  ient                                              ■    ing the   rains an   capping proce  ures)
                    must be specif e   except that concentration ranges may be                                                  Cleanup  proce  ures  (e.g.,  appropriate  techniques   or

                    use   in the  ollowing situations:                                                                     ■    neutralization,   econtamination, cleaning, or vacuum-


                    ●    A tra  e secret claim is ma  e,                                                                        ing; a  sorbent materials; an  /or equipment require    or

                    ●    T ere is batch-to-batch variation, or                                                                  containment/cleanup)

                    ●    Te SDS is use    or a group o  substantially similar
                         mixtures.



                    Chemicals where a trade secret is claimed                                                              SECTION 7: HANDLING AND STORAGE



               ■    A statement that the specif c chemical i  entity an  /or                                               T is section provi  es gui  ance on the sa e han  ling practices
                    exact percentage (concentration) o  composition has been                                               an   con  itions  or sa e storage o  chemicals. T e require

                    withhel   as a tra  e secret is require
                                                                                                                           in ormation consists o  the  ollowing:




               SECTION 4: FIRST-AID MEASURES                                                                               ■    Precautions  or sa e han  ling, inclu  ing recommen  a-
                                                                                                                                tions  or han  ling incompatible chemicals, minimizing

               T is section   escribes the initial care that shoul   be given by                                                the release o  the chemical into the environment, an   pro-


               untraine   respon  ers to an in  ivi  ual who has been expose                                                    vi  ing a  vice on general hygiene practices (e.g., eating,
               to the chemical. T e require   in ormation consists o                                                              rinking, an   smoking in work areas is prohibite  ).

                                                                                                                           ■    Recommen  ations  on  the  con  itions   or  sa e  storage,

               ■    Necessary f rst-ai   instructions by relevant routes o  expo-                                               inclu  ing any incompatibilities. Provi  e a  vice on specif c
                    sure (inhalation, skin an   eye contact, an   ingestion)                                                    storage requirements (e.g., ventilation requirements).


               ■    Description o  the most important symptoms or e  ects,
                    an   any symptoms that are acute or   elaye


               ■    Recommen  ations  or imme  iate me  ical care an   special                                             SECTION 8: EXPOSURE CONTROLS/PERSONAL
                    treatment nee  e  , when necessary
                                                                                                                           PROTECTION



               SECTION 5: FIREFIGHTING MEASURES                                                                            T is section in  icates the exposure limits, engineering con-

                                                                                                                           trols, an   personal protective measures that can be use   to
               T is section provi  es recommen  ations  or f ghting a f re                                                 minimize worker exposure. T e require   in ormation con-


               cause   by the chemical. T e require   in ormation consists o                                               sists o



               ■    Recommen  ations o  suitable extinguishing equipment,                                                  ■    OSHA  permissible  exposure  limits  (PELs),  American
                    an   in ormation about extinguishing equipment that is                                                      Con erence  o   Governmental  In  ustrial  Hygienists

                    not appropriate  or a particular situation                                                                  (ACGIH) threshol   limit values (  LVs), an   any other


               ■    A  vice on specif c hazar  s that   evelop  rom the chemical                                                exposure limit use   or recommen  e   by the chemical
                      uring the f re, such as any hazar  ous combustion pro  -                                                  manu acturer, importer, or employer preparing the sa ety

                    ucts create   when the chemical burns                                                                         ata sheet, where available


               ■    Recommen  ations on special protective equipment or                                                    ■    Appropriate engineering controls (e.g., use local exhaust
                    precautions  or f ref ghters                                                                                ventilation, or use only in an enclose   system)


                                                                                                                           ■    Recommen  ations  or personal protective measures to

               SECTION 6: ACCIDENTAL RELEASE MEASURES                                                                           prevent illness or injury  rom exposure to chemicals, such

                                                                                                                                as personal protective equipment (PPE) (e.g., appropriate

               T is section provi  es recommen  ations on the appropriate                                                       types o  eye,  ace, skin or respiratory protection nee  e

               response to spills, leaks, or releases, inclu  ing containment                                                   base   on hazar  s an   potential exposure)
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