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Kimia Tingkatan 5  Bab 1  Tindak Balas Redoks

            Tugasan       1


             1.  Hitung nombor pengoksidaan bagi unsur-unsur yang digariskan berikut:   TP  2
                Calculate the oxidation numbers for the following underlined elements:                                1
                 Contoh / Example:                       Penyelesaian / Solution:
                 KMnO 4                                                     KMnO 4    = 0
                                                         (+1) + Mn + 4(–2)  = 0                                       BAB
                                                                                     Mn = +7

                         +                      (b)     Fe 2 O 3                       2–
                  (a)     NH 4                                                 (c)     CO 3
                          NH 4    = +1                        Fe 2 O 3    = 0              CO 3   = –2
                      N + 4(+1)   = +1               2Fe + 3(–2) = 0                C + 3(–2) = –2
                            N  = –3                                   Fe = +3             C  = +4

                 (d)  HOCl                      (e)     K 2 Cr 2 O 7           (f)     Na 2 S 2 O 3
                             HOCl  = 0                        K 2 Cr 2 O 7  = 0             Na 2 S 2 O 3  = 0
                     (+1) + (–2) + Cl = 0            2(+1) + 2Cr + 7(–2) = 0        2(+1) + 2S + 3(–2) = 0
                                Cl  = +1                          Cr = +6                        S = +2


             2.  Berdasarkan nombor pengoksidaan yang diberikan, namakan sebatian mengikut sistem penamaan IUPAC.   TP  4
                Based on the given oxidation numbers, name the compounds according to the IUPAC nomenclature.
                       Sebatian          Nombor pengoksidaan                Sistem penamaan IUPAC
                       Compound             Oxidation number                   IUPAC nomenclature
                 Contoh / Example :    Fe = +2
                 Fe 2 O 3                                        Ferum(II) oksida / Iron(II) oxide
                 (a)  Cu 2 O           Cu = +1                   Kuprum(I) oksida / Copper(I) oxide
                 (b)  PbI 2            Pb = +2                   Plumbum(II) iodida / Lead(II) iodide

                 (c)  K 2 Cr 2 O 7     Cr = +6                   Kalium dikromat(VI) / Potassium dichromate(VI)

             5.  Seketul zink, Zn diletakkan ke dalam larutan kuprum(II) sulfat, CuSO 4  yang berwarna biru. Setelah 30 minit,
               larutan biru bertukar menjadi tak berwarna.
               A piece of zinc, Zn is placed into a blue copper(II) sulphate, CuSO 4   solution. After 30 minutes, the blue solution turns colourless.
                (a)  Nyatakan persamaan kimia seimbang bagi tindak balas redoks di atas.  TP  2
                   State the balanced chemical equation for the above redox reaction.
                   Zn(p) + CuSO 4 (ak) → ZnSO 4 (ak) + Cu(p)
                   Zn(s) + CuSO 4 (aq) → ZnSO 4 (aq) + Cu(s)
                (b)  Nyatakan persamaan ion bagi tindak balas redoks di atas.  TP  2
                   State the ionic equation for the above redox reaction.
                                 2+
                   Zn + Cu  → Zn  + Cu
                          2+
                (c)  Tulis persamaan setengah yang menunjukkan tindak balas pengoksidaan dan penurunan.  TP  2
                   Write the half-equations that show the oxidation and reduction reactions.
                                                          2+
                   •   Pengoksidaan / Oxidation:   Zn → Zn  + 2e –
                                                        –
                                                   2+
                   •   Penurunan / Reduction:   Cu  + 2e  → Cu
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