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(iii) Sample 4                      [1]          Paper  chromatography  is  used  to  identify  amino
                             1.6                                          acids.
                                 = 0.2
                             8.0                                       (d)  Electrolysis                     [1]
                             Sample 2                        [1]          Lithium ions are separated by gaining an
                             4.8                                          electron to form lithium [1] at the cathode.  [1]
                                 = 0.6
                             8.0                                                                             [1]
                    7  (a)  Draw 3 small circles on the chromatogram.  [1]    9  (a)  A substance that is composed of two or more
                         From the lowest to the highest:                  elements                           [1]
                         Yellow, red, blue with correct label   [1]         chemically combined              [1]

                      (b)  Water                             [1]       (b)  Must be in the correct order:
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                         The black ink is water-soluble (it is written in the          1  Dissolving         [1]
                         statement).                                      2  Filtration                      [1]
                      (c)  Different  solubilities  of  substances  to  the          3  Evaporation / Crystallisation   [1]
                         solvent used                        [1]       (c)  (i)  Condenser                   [1]
                         The attachment of substances to the paper  [1]            Arrow pointing into lower aperture
                      (d)  Draw a horizontal line below the baseline.  [1]    only                           [1]
                         The solvent level should not be above the baseline.   Water should go in from the lower aperture.
                         If  the  solvent  is  above  the  baseline,  substances          (ii)  The stopper is placed over the mouth of
                         cannot be separated properly.
                                                                              fractionating column.          [1]
                      (e)  The pencil marking cannot dissolve in water. [1]            Gases or vapour escape from the mouth of
                                                                              fractionating column.          [1]
                      (f)  Spot the colour on the baseline.   [1]
                         Let the solvent travel until the solvent front.  [1]         (iii) The mixture is flammable.   [1]
                         Dry the chromatogram.               [1]          (iv)  The temperature of the water bath cannot
                    8  (a)  Add a dilute acid.               [1]              exceed 100°C.                  [1]
                         Filter.                             [1]              Alcohols C and D have boiling points that
                         Copper does not react or dissolve. / Magnesium       are higher than 100°C.         [1]
                         reacts or dissolves, or forms salt.   [1]    10  (a)  (i)  Zn  / Zinc ions          [1]
                                                                                2+
                         Copper metal cannot react with dilute acid because
                                                                                2+
                                                                                       –
                         it  is  not  reactive.  However,  it  can  react  with          (ii)  Zn  + 2OH  ➞ Zn(OH)    [1]
                                                                                                  2
                         concentrated  acid.  Magnesium  reacts  with  dilute       (b)  (i)  No reaction / No change   [1]
                         acid.
                      (b)  Diffusion (through a membrane)    [1]          (ii)  A yellow precipitate is formed.   [1]
                         Nitrogen diffuses faster than oxygen.   [1]          Silver iodide is a yellow solid.
                         because it has the smallest M .     [1]          (iii) AgI                          [1]
                         M  N  = 28; M  O  = 32  r                   11  (a)  A white                        [1]
                             2
                           r
                                     2
                                   r
                         or                                               precipitate forms.                 [1]
                         Fractional distillation             [1]          It dissolves in excess of sodium hydroxide.  [1]
                         The mixture of air is cooled and turns into a
                                                                              +
                         liquid.                             [1]       (b)  NH                               [1]
                                                                             4
                         Nitrogen with a lower boiling point than       (c)  A pale blue                     [1]
                         oxygen will tend to evaporate faster.   [1]         precipitate forms.              [1]
                         Gases condense to become liquids.                It dissolves in excess of ammonia solution  [1]
                         or                                               and turns into deep blue solution.   [1]
                         Burn a named substance              [1]
                         to produce non-gaseous products     [1]       (d)  Add aqueous ammonia              [1]
                         Oxygen reacts / nitrogen does not react. Name       (e)  Fe                         [1]
                                                                            2+
                         the product of combustion.          [1]            –
                         Magnesium  can  be  used.  Magnesium  burns  and       (f)  Br                      [1]
                         reacts  with  oxygen  to  form  magnesium  oxide.       (g)  A white                [1]
                         Magnesium oxide is a solid. Nitrogen does not react          precipitate forms.     [1]
                         with oxygen in the same way.
                                                                       (h)  Add dilute aqueous sodium hydroxide   [1]
                      (c)  Chromatography                    [1]          and  then  some  small  pieces  of  aluminium
                         Use  of  locating  agent  /  Two  acids  move  at   foil.                           [1]
                         different  rates.  /  Leucine  travels  faster  than          Heat gently.          [1]
                         histidine.  /  Leucine  travels  higher  up  on  the
                         paper / further.                    [1]


                        Cambridge IGCSE  TM
                  174     Ace Your Chemistry







         Answers.indd   174                                                                                         3/4/22   3:54 PM
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