Page 57 - ACE YR IGCSE A TOP APPROACH TO CHEM
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(ii)  UV light                     [1]        (d)  (i)  A  process  of  making  a  long  chain  of
                                Provide the activation energy   [1]              organic compound               [1]
                                                                                 by using one type of monomer   [1]
                            (iii) Chloroethane / dichloroethane /
                                trichloroethane / tetrachloroethane /        (ii)   H   H
                                pentachloroethane / hexachloroethane  [1]
                                ClCH CH  / ClCH CH Cl / any correct                 C   C
                                               2
                                                  2
                                        3
                                     2
                                number of chlorine atom according to the            H   H   n
                                named molecule                 [1]
                                Note: The question requires the candidate to             Correct monomer        [1]
                                write the molecular structure. If the word used             Draw the arm to show continuous   [1]
                                is ‘draw’, the candidate should draw as below:   Step  1:  Draw  the  structure  of  ethene  but
                                              H   H                              change the C=C double bond to a single bond.
                                                                                 Step  2:  Draw  the  arm  at  the  side  of  both
                                          Cl  C   C  H                           carbon atoms.
                                                                                 Step 3: Add brackets and a “n” at the bottom
                                              H   H                              right.
                                This is an example of a drawn structure.         (iii) Polyethene               [1]
                         (e)  (i)  CH CH CH  + 5O  ➞ 3CO  + 4H O          (e)  (i)  They have the same molecular formula [1]
                                               2
                                                      2
                                                           2
                                          3
                                   3
                                      2
                                Correct formula                [1]               different structural formula   [1]
                                Balanced equation              [1]           (ii)   H   H  H   H  H
                            (ii)  Global warming               [1]
                                Carbon dioxide is a greenhouse gas that causes   H  C   C  C   C  C   H
                                global warming.                                     H          H  H             [1]
                       3  (a)  Contains a C=C double bond      [1]               Tips: Move the functional group which is the
                            The C=C double bond allows the addition reaction     C=C double bond to different locations.
                            to happen.                                    (f)  C H  + C H                       [2]
                                                                                       4
                                                                              4
                                                                                 10
                                                                                     2
                         (b)  Only one product is formed       [1]           or
                         (c)  (i)  Ethane                      [1]           C H  + C H                         [2]
                                                                                       6
                                                                                 8
                                                                                    3
                                                                              3
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                                                               [1]
                                                                             The  products  of  cracking  include  alkanes  and
                                C H
                                 2  6
                                                                             alkenes.
                            H   H                       H   H                Always  ensure  the  total  number  of  carbon  and
                                                                             hydrogen atoms in the products is the same as the
                            C   C  +  H   H          H  C   C  H
                                                                             reactant.
                            H   H                       H   H           4  (a)  (i)  Fermentation               [1]
                                Nickel                         [1]           (ii)  Yeast                        [1]
                            (ii)  Ethanol                      [1]               25°C                           [1]
                                CH CH OH                       [1]               Yeast  is  used  to  catalyse  the  reaction  in  the
                                   3  2                                          absence of air.
                            H   H                     H  H                       The high temperature used will denature the
                                                                                 yeast.
                            C   C +  H  O  H      H   C  C   O  H
                                                                             (iii) High percentage of ethanol   [1]
                            H   H                     H  H                       When  the  percentage  of  ethanol  reaches  a
                                                                                 certain level, the yeast will be denatured.
                                Phosphoric acid                [1]
                                                                          (b)  (i)  Adding water                [1]
                            (iii) Dibromoethane                [1]
                                                                             (ii)  C H  + H O ➞ C H OH
         H   H                      H  H                                          2  4  2     2  5
                                                                                 Correct reactants              [1]
         C   C +  Br  Br        Br  C  C   Br                                    Correct product                [1]
         H   H                      H  H                       [1]           (iii) 300°C                        [1]
                                                                                 60 atm / 6000 kPa              [1]
                             H  H                      H   H                     Phosphoric acid                [1]
                             C  C +  Br  Br        Br  C   C  Br          (c)  Biological method
                                                                             Advantage                          [1]
                             H  H                      H   H                 •  Use of renewable resources
                                UV light                       [1]           Maize or sugarcane is used in fermentation.
                                                                             These plants can be planted again and again.



                                                                                                     Answers    169







         Answers.indd   169                                                                                         3/4/22   3:54 PM
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