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Chemistry Term 3  STPM  Chapter 14 Introduction to Organic Chemistry
                 (b)  CH 3 CH 2 CH 2 CH 2 Br  1-Bromobutane
                              *
                     CH 3 CH 2 !CH!CH 3      2-Bromobutane is chiral
                             &
                              Br
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                          CH 3
                          &
                     CH 3 —CH—CH 2 Br        2-Methyl-1-bromopropane

                          CH 3
                          &
                                             2-Bromo-2-methylpropane
                     CH 3 —C—CH 3
                          &
                          Br


                14.3  Functional Groups: Classification and Nomenclature

                 Section A   Multiple-choice Questions

              Question 1

                The structural formula of cholesterol is shown below:

                                            H C               CH
                                             3
                                                C               3
                                             CH 3          CH 3
                                      CH
                                        3


                             HO

                Which of the following statements is not correct regarding cholesterol?
                A  The hybridisation of the carbon atoms includes sp  and sp  only.
                                                                 3
                                                           2
                B  Its molecular formula is C 27 H 46 O 2 .
                C  It contains the hydroxy and alkene functional groups.
                D  The molecule is not planar.


              Answer: B
                 The structural formula shows only one oxygen atom. Thus, B cannot be correct.
         Term
                 For A, there are only two types of carbon-carbon bonds in the molecules. They
        3        are C—C (sp ) and C=C (sp ).
                            3
                                        2
                 For D, molecules with  sp  hybridised carbon atoms are tetrahedral (three
                                       3
                 dimensional).
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         14 Q&A STPM Chem T3 Layout.indd   346                                 4/19/19   5:29 PM
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