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                   IN FORMATIVE ZONE...’     Form 5     Chemistry   Chapter 2 Carbon Compound
                                              2.3  Chemical Properties and     3.  When the molecular size of an alkane increases,
                                                Interconversion of Compounds   molecules of alkanes burn with sootier flames.  5     Chemistry   Chapter 2 Carbon Compound
                                                          it becomes more difficult to burn. Large  Form
                                                between Homologous Series  This is because the number of carbon atoms per
                  Tag placed at the end of    Chemical Properties of Alkane  molecule increases as the molecular size of an   2.4
                                                          alkane increases. The percentage of carbon by
                                               1.  Alkanes are  unreactive and do not react with   mass in the alkane molecule also increases.
                                            CHAP.  most chemicals.    1.  Name the following compound using the IUPAC nomenclature system.  C2  CHAP.
                  examples to guide students in    2.  Alkanes  are  saturated  hydrocarbon  Example 5   (a)        H  H  H     (b)   H |  2
                                            2
                                                                      |  |  |
                                              compounds. Each carbon atom in an alkane
                                              molecule  is  already bonded  to  a maximum   Explain why butane, C 4 H 10  burns with more sooty  CHAP.  H–C–C–C–H       H–C–H |  CHAP.
                                                                                H    H
                                                                         |
                                                                      |

                                              number  of  atoms.  The  strong  C-C  and C-H
                                                                                |
                                                         flame compared to ethane, C 2 H 6 .

                                                                      H   H
                  answering related questions in  bonds need a lot of energy to break.  [Relative atomic mass: H = 1; C = 12]  2         H–C–H | H  H–C–C–C–H  2
                                                                                   |

                                                                                |
                                               3.  Alkanes undergo two types of reactions:
                                                         Solution
                                                                                H   H

                                              (a)  Combustion
                                                                                 |
                                              (b)  Substitution  Percentange of carbon by mass in butane, C 4 H 10    H–C–H
                                                                                 H
                  Formative Zone.            Combustion reaction  =  4(12) + 10(1)  × 100% = 82.76%    2.  Draw the structural formula for each of the following organic compounds.  C2
                                                          4(12)
                                               1.  Alkanes burn completely in excess oxygen, O 2    Percentage of carbon by mass in ethane, C 2 H 6  (a)  2-methylbutane
                                                          2(12)
                                                                    (b)  2-methylpropene
                                              to produce  carbon  dioxide, CO 2  and  water,   =  2(12) + 6(1)  × 100% = 80%
                                              H 2 O. The combustion of alkanes produces a lot        3.  Name the following using the IUPAC nomenclature system.
                                              of heat. Hence, alkanes are used as fuels.  The  percentage  of  carbon  by  mass  of  butane,   (a)      H  H    H     (b)      H  H  H  H
                                              Example:   C 4 H 10   is  higher.  As  a  result,  it  burns  with  more      |  |  |     |  |  |  |
                                              CH 4 (g) + 2O 2 (g) → CO 2 (g) + 2H 2 O(l)  sooty flame.  H–C–C=C–C–H  H–C=C–C–C–C–H
                                                                        |  |
                                                                                  |  |  |

                                                                      |
                                                Methane                  H   H  H  H  H  H
                                              2C 2 H 6 (g) + 7O 2 (g) → 4CO 2 (g) + 6H 2 O(l)  Substitution reaction    4.  Draw the following isomers of pentene.
                    ©PAN ASIA PUBLICATIONS
                                                Ethane     1.  A  substitution reaction occurs when an atom   (a)  Pent-2-ene
                                                  Try Question 1 in Formative Zone 2.3
                                                          in a molecule.
                                               2.  Incomplete combustion occurs in limited   or a group of atoms is substitute by other atoms   (b)  2-methylbut-1-ene
                                                                    (c)  3-methylbut-1-ene
                                              supply of  oxygen, O 2 . Alkanes burn in  sooty     2.  In this reaction,  each hydrogen atom in an   (d)  2-methylbut-2-ene  FORMATIVE ZONE
                                              flame and produce a mixture of  carbon, C   alkane molecule is substituted by a  halogen     5.  Name the following using the IUPAC nomenclature system.  C2
                                              particle  (soot),  carbon  monoxide, CO gas,   atom in the presence of sunlight or ultraviolet   (a)      H   H     (b)      H
                                              carbon dioxide, CO 2  gas and water, H 2 O.  (UV) rays as the catalyst.      |   |     |
                                              Example:    Example:    H–C–CC–C–H |       H–C–H   H
                                                                      |

                                              2CH 4 (g) + 3O 2 (g)   → 2CO(g) + 4H 2 O(l)  Methane,  CH 4  reacts with  chlorine, Cl in the      H   H  |
                                                Methane 5 Form  presence of sunlight or UV rays to produce four   H–CC–C–C–H
                                              CH 4 (g) + O 2 (g)   → C(s) + 2H 2 O(l)  products as shown in Figure 2.9.       H  H Questions to test
                                                                                  |  |
                                                  Chemistry   Chapter 4 Polymer

                                                Ethane         H
                                                 SPM Simulation HOTS Questions    H – C – H    6.  Draw the structural formula of pent-2-yne.  C2
                                                             l
                                                               l     7.  Name the following using the IUPAC nomenclature system.  C2
                                                             H
                                                  1.  Figure  1 shows the structural formula of
                                                             Methane
                                              To balance a chemical equation:  A     Melting point  (a)      H  H     (c)      H  H  H students' understanding
                                              Step 1:    compound Z which is used to make a pipe.  B  Density     |  |     |  |  |
                                                              Cl 2 , UV ray
                                              Check the number of carbon and hydrogen atoms   C  Empirical formula  H–C–C–O–H  H–C–C–C–O–H
                                                                                H–C–H at the end of each
                                              in the molecular formula of alkane. Balance the   D  Molecular formula       |  | H  H       |  H   H   |
                                                  H Cl H Cl H Cl
                                                  C C C C C C
                                              number of carbon atoms in CO 2  and the number of

                                                               Cl
                                              hydrogen atoms in H 2 O by adding a number in front        H l       H Examiner’s comment:       Cl l  |
                                                  H H H H H H
                                              of each formula.  Compound Z  H – C – Cl  H – C – Cl  H – C – Cl  Cl – C – Cl  (b)   H

                                                            l Both  substances have the empirical
                                                               l


                                              Step 2:         H l       Cl molecular mass, so the density is higher        H  H  H  H
                                                            l formula of CH 2 .  Substance  S has bigger
                                                               l
                                                                 l

                                                                 Cl
                                                                      |  |  |  |
                    SPM SIMULATION            Balance the number of oxygen atoms in O 2 . If the        Chloromethane  Dichloromethane  Trichloromethane  Tetrachloromethane    8.  Draw the following isomers of butanol.  C2  suptopic.

                                                               Cl
                                              Check the number of oxygen atoms in CO 2  and H 2 O.
                                                                      H–C–C–C–C–O–H
                                                    Figure 1
                                                            than R. With bigger molecular size, forces
                                                                      |  |  |  |

                                                            of attraction between molecules become
                                                 Which of the following is the structural formula
                                                         Figure 2.9 Products of substitution reaction of methane
                                              number needed to add is a fraction, then multiply all
                                                                      H  H  H  H

                                                            stronger. Therefore, the melting point of
                                                 of the monomer of compound Z?  C2
                                              the numbers in front of the formulae by 2.
                                                            S is higher.
                                                 A
                                                            Answer: C
                    HOTS QUESTION             376    H  Cl             3.  Figure  3 shows the raincoat which is made  (a)  Butan-2-ol
                                                                  2.3.1
                                                       C   C
                                                                    (b)  2-methylpropan-2-ol
                                                      H  H n
                                                            from a synthetic polymer, polyvinyl chloride,
                                                            PVC.
                                                 B
                                                       H  Cl
                                                   C   C            404
                                               CHAP.       H  H                                  CHAP.
                                               4  C                                              4
                   Provides complete solution         H   C   C   H
                                                  H  Cl




                                                  H  H
                   with examiner’s comment       D        H  Cl
                                                   C   C

                                                   H  H                 SPM
                   to help students to answer    Examiner’s comment:  (a)  State the name of the monomer for   MODEL PAPER
                                                               Figure 3
                                                 Monomer  of compound  Z (polymer) must
                                                 have a carbon-carbon double bond, C = C.  polyvinyl chloride, PVC.  C1
                                                 Structural  formula  in  Answer  A  is another   (b) Draw the structural formula for the   Paper 1
                                                            monomer.  C2
                   HOTS questions.               but not the monomer of compound Z.  (c)  State  one reason why polyvinyl chloride,   Instruction: Answer all questions.  [40 marks]
                                                 simplified  way  to  represent  the  polymer  Z
                                                            PVC  should not  be disposed by  open
                                                 Answer: B
                                                            burning?   C3
                                                  2.  Figure 2 shows the polymerisation process.    1.  What is the meaning of nanotechnology?     5.  The   following  statement  refers  to  the
                                                             Examiner’s comment and answer:  A  The study of chemical bonds between metal   characteristics of an element in the Periodic Table
                                                       H  H      H  H    (a) Vinyl chloride // Chloroethene  atom and non-metal atom.  of Elements.

                                                   C   C        C   C   B  The manipulation of materials on an atomic


                                                              H  H n    (b)  H  Cl    or molecular scale.  • Brown colour and soft solid.
                                                   H  H       H   C                 • Reacts with water to produce alkaline
                                                   R  S           H  H    C  The study the importance of food additives   solution.
                                                                         in food processing industry and the
                                        Form
                                                                                    • Burn in oxygen to produce a white solid.
                    SUMMATIVE ZONE       4     Chemistry   Chapter 7 Rate of Reaction  Figure 2  (c) Burning  of polyvinyl chloride, PVC   D  The development and the application of   Which element has the above characteristics?
                                                                         evolution of food processing technology.
                                                             will release pollutant and acidic gas
                                                 Which of the following is similiar for substances
                                                                         products or equipment, and a system to
                                                             such as hydrogen chloride gas, HC
                                                 R and S?  C2
                                           3.  Diagram below shows a graph of volume of gas against time in a reaction. 60 cm 3  of hydrogen gas, H 2
                                          is collected when excess magnesium powder, Mg reacts with 50 cm 3  of 0.1 mol dm –3  nitric acid, HNO 3 . to the atmosphere.  conserve the environment.  A  D
                                                                          2.  Figure  1 shows two situations occur when   B  C
                                                Volume of gas (cm 3 )   sunlight is shining on the glass X.
                   Question of various levels   474 90                               6.  Which statement explains the effective collision?
                                                                                    A  The collision which takes place after a
                                                60                             Darker in   reaction.
                                              Answer (a)               SPM MODEL PAPER  sunlight  B   The collision which takes place before a
                   of thinking skill to evaluate   30                     Glass X   C   The collision that causes a reaction.
                                                                                    reaction.
                                                                            Figure 1
                                                0       Time (s)        What is the type of glass X?  D   The collision produces less activation
                                                                                    energy.
                   student’s understanding of                           A  Fused glass    7.  Figure  2 shows a glass cookware that usually
                                          (a)  On the same axes, sketch the curve that you would expect to obtain if 25 cm 3  of 0.2 mol dm –3

                                                                        B   Soda-lime glass
                                           nitric acid, HNO 3  reacts with excess magnesium powder, Mg.
                                                                                    used in the kitchen.

                                          (b)  Explain your answer in 3(a).
                                                                        C   Borosilicate glass
                                                                        D   Photochromic glass
                   each topic.            Examiner’s comment  1000  1000    3.  The following statement refers to an element in
                                          Number of moles of HNO 3 , n =  0.1(50)  = 0.005 mol; Number of moles of HNO 3 , n =  0.2(25)
                                                                        the Periodic Table of Elements.
                                          = 0.005 mol
                                          Number  of moles of nitric acid, HNO 3  used in both experiments are the same, the number of   • Located in Period 3 in the Periodic Table of
                                                                         Elements
                                          moles of hydrogen gas, H 2  produced will also be the same, which is 60 cm 3 . Concentration of nitric   • Reacts with water to produce acidic   SPM MODEL PAPER
                                                                         solution and bleaching agent
                                          acid, HNO 3  in the second experiment is higher. So, the rate of reaction is higher. That is why the   Figure 2
                                          gradient of the curve will be steeper.  • Reacts with iron wool to produce a brown   Which substance is added to the glass to make it
                                                                         solid      suitable for making the cookware?
                                                                                    A  Lead(II) oxide, PbO
                                                                        Which  of  the  following  shows  the  electron   B   Boron oxide, B 2 O 3
                                                                        arrangement of the element?  C   Natrium carbonate, Na 2 CO 3
                                                                        A  2.8.4   C  2.8.7  D   Aluminium oxide, Al 2 O 3
                                                                          4.  Water molecule combines with hydrogen ion to  SPM-oriented practice
                                                                             D  2.8.8
                                                                        B  2.8.5
                                                   Paper 1                           8.  Atom W has 4 neutrons and a nucleon number of
                                                                                    7. Which of the following is the correct symbol
                                          1.  Which of the following is a fast reaction?  C1  form hydroxonium ion, H 3 O + . What is the type   for atom W?
                                          A  Fermentation  SPM Clone  3.   Oxygen gas, O 2  is produced from the   of the chemical bond formed?  A   7 4 W    C   3 4 W
                                                                             C   Metallic bond
                                                                                    B   7 W
                                                                                     4
                                          B  Photosynthesis  decomposition of sodium chlorate(I), NaOCl   A  Dative bond   D   Hydrogen bondbased on latest SPM
                                                                                        D   7 3 W
                                          C  Formation of stalagmites  in the presence of manganese(IV) oxide, MnO 2 .   B   Ionic bond
                                          D  Combustion of magnesium  The following shows the chemical equation of the   524
                                         SPM Clone  2.   The reaction between sodium thiosulphate,      reaction.  MnO 2  format to assess students
                                          Na 2 S 2 O 3  and sulphuric acid, H 2 SO 4  is represented       2NaOCl(aq)     2NaCl(aq) + O 2 (g)
                                          by the following equation:     Figure 1 shows the graph of volume of oxygen gas
                                            Na 2 S 2 O 3 (aq) + H 2 SO 4 (aq) → Na 2 SO 4 (aq) + S(s) +   against time.
                                                                                          CHAP.
                                        CHAP.   SO 2 (g)    + H 2 O(l)  Volume of oxygen gas (cm 3 )  on all the topics learnt in
                                        7     Which of the following is the most suitable   7
                                          method to determine the rate of reaction?  C2
                                          A  Determine the change in temperature of the
                                           solution with time.                   Form 4 & 5 textbooks.
                                          B  Determine the volume of water, H 2 O
                                           produced with time.
                                          C  Determine the production of a fixed quantity   0  Time (s)  Form
                                           of sulphur, S precipitate with time.  Figure 1  4
                                                              Chapter 4 The Periodic Table of Elements
                                          D  Determine the change in the concentration of      Why the gradient of the curve decrease with   Chemistry
                                           sodium sulphate, Na 2 SO 4  with time.  time?  C2
                                         264         Reinforcement & Assessment of Science Process Skill
                                                    Reinforcement exercise of science process skills in preparation for the Kertas Amali Bersepadu.
                                                    In this experiment you are required to investigate the properties of three types of oxides of elements in period
                                                    3 in the Periodic Table of Elements based on the reaction with alkali and acid solutions.
                                                    You are provided with the following materials:
                                                    •  K1 = Oxide P
                                                    •  K2 = Oxide Q
                                                    •  K3 = Oxide R
                                                    •  L1 = Sodium hydroxide solution, 2.0 mol dm –3
                    REINFORCEMENT & ASSESSMENT      •  L2 = Nitric acid, 2.0 mol dm –3  ANSWERS  Complete Answers
                                                                                    https://bit.ly/3sn6L0o
                                                    Carry out the experiment according to the following instructions:
                                                      1.  Put 2 spatula of substance K1 into two different test tubes.
                                                      2.  Pour 5.0 cm 3  solution L1 into the first test tube.  Form 4  (b)  (i)  Vinegar; salt; baking powder
                    OF SCIENCE PROCESS SKILL          3.  Pour 5.0 cm 3  solution L2 into the second test tube.  Chapter 1  Introduction to Chemistry  (c)   Chemist; doctor
                                                                                 (ii)  Vinegar: preserves food

                                                                                  Salt: gives salty taste
                                                      4.  Heat the mixture in each test tube slowly while stirring with a glass rod.
                                                                                  Baking powder: raises the dough
                                                      5.  Record the solubility of substance K1 in each test tube.
                                                                         1.1
                                                                          CHAP.
                                                                                 can be poured directly into the sink. Concentrated
                        CHAP.                         6.  Repeat the experiment by replacing substance K1 with K2 and K3.    1.  A field of science that studies the structures, properties,   (d)  Hydrogen peroxide waste with low concentration
                                                                                 hydrogen peroxide wastes need to be diluted with
                                                                          4
                        4                                      Observation  compositions and interactions between matter.  water. Then, it is added with sodium sulphite for the
                                                                       2.  Herbicide; Hormone  purpose of decomposition before being poured into the
                                                                       3.
                                                        Oxide  Reaction with nitric acid, HNO 3  Reaction with sodium  With nanotechnology, sunscreens are no longer oily     2.  (a)  (i)  Presence of water and oxygen
                                                                                 sink.
                                                                  hydroxide solution,  nowadays and are colourless when applied to the skin.
                   Questions for students to master the   Oxide P (K1)  NaOH   4.  (a)  Cosmetic consultant        (b)  Water and oxygen are needed for iron rusting.
                                                                                 (ii)  Rusting of iron nail
                                                                                 (iii) Type of nail
                                                                      (b)  Dietitian
                                                                      (c)  Pathologist
                                                                      (d)  Veterinarian
                                                                                 (c)
                                                                                     Observation
                   science process skill (SPS) presented   Oxide Q (K2)    1.  A systematic scientific method used to solve science related   Test tube A B  Iron nail does not rust.
                                                                         1.2
                                                                                   Iron nail rusts.
                                                                      problems.
                                                       Oxide R (K3)    2.  (a)  When the temperature increases, the mass of salt   C  Iron nail does not rust.
                   in Science Practical Test. Scan the QR     Table 1  (b)  Manipulated variable: Temperature  Section B (d)  Oxygen and water must be present for the iron nail to
                                                                      dissolved also increases.
                                                                                 rust.
                                                                      Responding variable: Mass of salt dissolved
                                                    (**Complete Table 1 with reference to the Simulation Experiments and Sample Results given)

                   code below to get Tip dan Teknik   Based on the experiment conducted:    1.  •  Do not eat, drink, chase or run in the laboratory.    3.  (a)  The scientific method is a systematic approach to solve   ANSWER FORM 4  ANSWERS
                                                                         1.3
                                                                                 problems in science.
                                                                                 (b)
                                                      1.  State the following variables based on the experiment above:
                                                                                  Making an observation
                                                                      •  Do not pour the chemicals back to the reagent bottles.
                                                     (a)  Manipulated:
                                                                      •  Do not point the mouth of the test tube at your face or
                                                     (b)  Responding:     2.  •  Keep flammable substances away from the heat source.  Making an inference
                   Prihatin Murid in answering Science   (c)  Control:     3.  (a)  To carry out experiment that involves the release of   Identifying the problem
                                                                      at other people.
                                                                      toxic vapours, gases that can cause combustion or gases
                                                                      with pungent smell.
                                                      2.  Based on the results of the experiment, classify oxides P, Q and R into the table below according to their   Making a hypothesis
                                                     respective properties.
                                                                      (b)  To remove dirt, oil, chemicals or microorganisms from
                                                                      the hands.
                   Practical Test.                      Amphoteric  Base  Acid    4.  (a)  Kept in paraffin oil to prevent reaction between this  Answers are provided. Scan
                                                                                  Identifying the variables
                                                                      (c)  To wash and clean the body if accident happens on
                                                                      parts of the body. It is also used to put out fire at any
                                                                                  Controlling the variables
                                                                      part of the body if there is fire.
                   Tip dan Teknik                             Table 2    5.  Mercury poisoning is a phenomenon when a person is   Planning an experiment
                                                                      chemical with moisture, water and air.
                                                                      (b)  Kept in dark bottles to avoid the exposure of sunlight.
                                                                      exposed to mercury in a certain amount. Two symptoms of  QR code to get Complete
                                                                                   Collecting data
                                                                                   Interpreting data
                   Prihatin Murid                                     mercury poisoning are vomiting and difficult in breathing.  Making a conclusion
                                                                        113
                                                                             5.  C Answers with explanations for
                                                                     Paper 1
                                                                       1.  A   2.  A   3.  C  8.  D   4.  B   10.  C  Writing a report
                                                                       7.  B
                                                                           9.  B
                                                                       6.  B
                                                                                Section C
                   https://bit.ly/349VB5H                             11.  B   12.  C   13.  A   14.  C   15.  D  objective questions.
                                                                                  4.  (a)  (i)  Ammonium nitrate / Urea

                                                                                 (ii)  Occupation A: Pharmacist
                                                                     Paper 2
                                                                                  Occupation B: Pathologist
                                                                     Section A     (b)   •  Inform the accident to the teacher immediately.
                                                                       1.  (a)  Chemistry is defined as a field of science that       •  Make the spill area as a restricted area for students.
                                                                      studies the structures, properties, compositions and       •  Try to stop the spill from spreading to other areas
                                                                      interactions between matter.  using sand to border it.
                                                                                         541
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