Page 58 - Spotlight A+ Form 4 & 5 Chemistry KSSM
P. 58

Chemistry   Answer
             Paper 2                                           Element   Carbon, C  Hydrogen, H  Oxygen, O
             Section A
               1.  (a)  To remove the layer of the magnesium oxide on its   Mass (g)  54.55  9.09  36.36
                   surface.
                  (b)  To allow the oxygen to enter the crucible for the   Number of moles    54.55       9.09      36.36
                   complete combustion of magnesium.        of atoms        12       1           16
                  (c)  (i)                                                = 4.546  = 9.09      = 2.273
                       Element   Magnesium, Mg  Oxygen, O
                                  22.30 – 20.50   23.50 – 22.30            4.546       9.09    2.273
                       Mass (g)                             Simplest ratio   2.273   2.273     2.273
                                     =1.80      = 1.2
                                                                          = 2      = 4         = 1
                       Number of
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                       moles of      1.8   = 0.075  1.2   = 0.075        Thus, the empirical formula of compound Y is
                       atoms       24         16                     C H O.
                                                                      2
                                                                       4
                                                                  (ii)  Assume that the molecular formula of Y
                       Simplest ratio  1         1                   = (C H O) n
                                                                        2
                                                                         4
                        Thus the empirical formula of magnesium oxide is         Given that the molecular mass of (C H O)  = 88
                                                                                            2
                                                                                                n
                                                                                              4
                       MgO.                                          n[2(12) + 4(1) + 16] = 88
                      (ii)  2Mg(s) + O (g) → 2MgO(s)                           44n = 88
                              2
                  (d)  (i)                                                       n =   88
                                                                                    44
                    Glass tube
                                 Metal oxide W                                   n = 2
                   Rubber                                            Therefore, the molecular formula of compound Y
                   tubing
                                      Ethanol,  Glass tube           = (C H O)
                Air hole   Spirit                                       2  4  2
                                      C H OH                         = C H O
                           lamp        2  5                            4  8  2
               Glass tube
                                                Hydrochloric   Section B
                  Water                         acid          4.  (a)  (i)  The molecular formula of a compound shows the
                                                Zinc, Zn             actual number of atoms of each element present in
                                                                     a molecule of the compound.
                                                granules              (ii)  The relative molecular mass of glucose
           ANSWER FORM 4    2.  (a)  The empirical formula of a compound is the chemical         (b)  (i)  Consider 100 g of compound Q.  2
                               Wooden block
                                                                     = 6(12) + 12(1) + 6(16)



                   (ii)  The hydrogen gas is allowed to flow through the
                                                                     = 180
                       apparatus for 10 to 15 seconds to remove all the
                                                                     A molecule of glucose consists of 6 carbon atoms,

                       air.
                                                                     12 hydrogen atoms and 6 oxygen atoms.

                                                                     The empirical formula of glucose is CH O.
                   formula that shows the simplest ratio of the number of
                   atoms of each element in the compound.
                                                                        Element
                       hydrogen.
                                                                                              14.29%

                                                                                    85.71%
                   (ii)  The heating, cooling and weighing steps are
                    (b)  (i)  Method I. Magnesium is more reactive than   Percentage  Carbon, C  Hydrogen, H
                       repeated until a constant mass is obtained.    Mass (g)      85.71      14.29
                  (c)  (i)  Mass of copper
                        = 61.71 – 55.31 = 6.4 g                       Number of      85        14.29
                      (ii)  Number of moles of copper                 moles of atoms   12       1
                       =   6.4   = 0.1 mol                                           = 7.1425  = 14.29
                        64
                      (iii)  Mass of oxygen                                         7.1425      14.29
                        = 63.31 – 61.71 = 1.6 g                       Simplest ratio  7.1425   7.1425
                      (iv)  Number of moles of oxygen                               = 1       = 2
                       =   1.6   = 0.1 mol                            Thus, the empirical formula Q is CH . 2
                        16
                      (v)  0.1 mol of copper atom combines with 0.1 mol   (b)  (ii)  Assume that the empirical formula of Q = (CH )
                                                                                                   2 n
                       of oxygen atom. Thus, 1 mol of copper atom                              = 42
                       combines with 1 mol of oxygen atom. Empirical              Given that the relative molecular mass of
                       formula of copper oxide is CuO.               (CH )   = 42
                                                                        2 n
               3.  (a) The molecular formula is the chemical formula that              n[12+ 2(1)] = 42
                   shows the actual number of atoms of each element                  14n = 42
                   found in a molecule of a compound.                       n =   42
                  (b)  C H 12                                                  14
                                                                            n = 3
                    6
                  (c)   6(12) + 12(1) = 84                                    Therefore, the molecular formula of compound Q

                  (d)  CH 2
                  (e)   (i) Consider 100 g of compound Y.              = (CH )
                                                                         2 3
                                                                       = C H
                                                                       3  6
              546                                                                                                                                                                                                 547
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