Page 21 - Modul A+1 Kimia Tingkatan 5
P. 21

(ii)                           H                   (c)  C H  +  19  O  → 6CO  + 7H O         [1]
                                                                                2
                                                                                   2
                                                                           6
                                                                            14
                                                                                              2
                                                                                          2
                                                H  C   H                  Jisim molar/ Molar mass = 6(12) + 14(1) = 86    [1]
                                                                                                    8.6
                            H   H  H  H         H      H                  Bilangan mol/ Number of moles, n =   86   = 0.1    [1]
                                                                          1 mol C H  → 6 mol CO
                         H  C   C  C  C  H   H  C  C   C  H                    6  14        2
                                                                         1 mole of C H  → 6 moles of CO 2
                                                                                    14
                                                                                  6
                            H   H  H  H         H  H   H                  0.1 mol C H  → 0.6 mol CO 2
                                                                                 6
                                                                                  14
                                                                          0.1 mole of C H  → 0.6 moles of CO
                               2-butena        2-metilpropena                      6  14  3         2
                               2-butene        2-methylpropene            = 0.6 × 24 = 14.4 dm                   [1]
                                                           [4]
                    (iii)  1.  2 cm  larutan  kalium  manganat(VII),  KMnO    Kertas 3/ Paper 3
                               3
                                                             4
                           berasid dituang ke dalam dua tabung uji.    1.
                           2 cm   of  acidified  potassium  manganate(VII),
                               3
                           KMnO  solution is poured into two test tubes.              Pemerhatian/ Observation
                                4
                         2.  Kedua-dua gas dialirkan  ke dalam  tabung   Eksperimen  Sebatian organik P  Sebatian organik Q
                           uji  yang  mengandungi  larutan  kalium  Experiment  Organic compound P  Organic compound Q
                      ©PAN ASIA PUBLICATIONS
                           manganata(VII),  KMnO 4   berasid  secara
                           berasingan.                                           Perang kepada
                           Both  gases  is  flowed  into  separate  test  tubes   I  tidak berwarna  Tiada perubahan
                           containing acidified potassium manganate(VII),      Brown to colourless   No change
                           KMnO  solution.
                                4
                         3.  Warna ungu larutan akan dinyahwarnakan oleh          Ungu kepada
                           gas P.                                                                  Tiada perubahan
                           The purple colour of the  solution  will  be   II     tidak berwarna      No change
                           decolourised by gas P.                              Purple to colourless
                         4.  Gas Q tidak memberi kesan kepada warna ungu                                         [4]
                           larutan.                                   (a)  (i)   Sebatian Q/ Compound Q          [2]
                           Gas Q have no reaction with the purple colour      (ii)  Sebatian P/ Compound P
                           of the solution.                [4]        (b)  (i)   Heksena/ Hexene                 [2]
                                                                          (ii)  Heksana/ Hexane
                 (b)  (i)   C H OH + 2[O] → C H COOH + H O   [1]      (c)  (i)   1, 2-dibromoheksana/ 1, 2-dibromohexane  [2]
                            9
                                          7
                                                   2
                          4
                                        3
                         Pengesteran/ Esterification       [1]            (ii)  Heksan-1, 2- diol/ Hexan-1, 2-diol
                                                                      (d)  Tindak balas penambahan/ Addition reaction   [1]
                                   H
                         CH  CH  CH  C  O  CH CH  CH  CH
                           3  2  2       2  2   2  3                 BAB    3
                           Butil butanoat/ Butyl butanoate  [2+1]
                    (ii)  C H  + 6O  → 4CO + 4H O          [1]    Soalan Berformat SPM
                          4  8  2 4(12)  2   2
                         % C =   4(12) + 8(1)   × 100%     [1]    Kertas 1/ Paper 1
                            = 85.7 %                       [1]      1.  B    2.  C     3.  C     4.  B     5.  B
                                                                    6.  C    7.  A     8.  C     9.  D    10.  C
             Bahagian C/ Section C
               4.  (a)                                            Kertas 2/ Paper 2
                                   Kumpulan   Formula             Bahagian A/ Section A
                        Formula am
              Sebatian   General   berfungsi  struktur   Nama       1.  (a)  Eksotermik. Membebaskan haba ke persekitaran kerana
              Compound             Functional   Structural   Name        ΔH mempunyai tanda negatif.
                         formula                                          Exothermic. Released heat to surrounding because  ΔH
                                     group     formula
                                                                         has a negative sign.                    [2]
                                               H  H  H  Propanol      (b)  Ikatan kovalen H–H dan ikatan kovalen Cl–Cl./ Covalent
                 A      C H 2n+1 OH  –OH     H  C O  C H  C H  H  Propanol  bond H–H and covalent bond Cl–Cl.    [2]
                          n
                                               H                      (c)  Jumlah kandungan tenaga bahan tindak balas lebih tinggi
                                                                         berbanding jumlah kandungan tenaga hasil tindak balas
                                                                          Total energy content of the reactants is higher than total
                                               H  H  H  Propena
                 B        C H        C=C     H  C  C  C  H               energy content of the products.         [2]
                           n  2n                        Propene
                                                   H                2.  (a)  Haba yang dibebaskan apabila  1 mol kuprum, Cu
                                                                         disesarkan daripada larutan kuprum(II) sulfat, CuSO oleh
                                                          Asid           zink, Zn.                             4
                                               H  H  O  propanoik         Heat released when 1 mole of copper, Cu is displaced from
                 C     C H 2n+1 COOH  –COOH  H  C  C  C  OH  Propanoic   copper(II) sulphate, CuSO  solution by zinc, Zn.   [1]
                        n
                                               H  H                   (b)  Eksotermik/ Exothermic   4            [1]
                                                          acid
                                                                      (c)  (i)   θ = mcθ
                  (b)                                                          = 50 × 4.2 × 8
                           Serpihan porselain  Propena                         = 1680 J
                           Porcelain chips  Propene
                                                                               = 1.68 kJ                         [1]
                                                                          (ii)  Bilangan mol CuSO  / Number of moles of CuSO 4
                                                                                             4
                                                                              =  mv   = 0.01
                              Panaskan                                          1000
                              Heat                                            =  0.2 × 50   = 0.01 mol
                      Wul kaca direndam  Air                                     1000
                       dalam propanol  Water               [3]                Haba penyesaran/ Heat of displacement
                      Glass wool soaked                                       =  0.01 mol   = –168 kJ mol        [2]
                                                                                 1.68 kJ
                      in propanol
                                                                                                 –1
           Jawapan         C H OH → C H  + H O             [1]        (d)  Zn + CuSO  → ZnSO  + Cu    ∆H = –168.0 kJ mol   [1]
                                                                                                              –1
                                                                                         4
                                                                                  4
                                    2
                     3
                              3
                       7
                                6
                                                             MG-12
   16   17   18   19   20   21   22