Page 365 - Basic Principles of Textile Coloration
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354 REACTIVE DYES

                      Br                              Cl  F
Dye NH CO C CH2                              Dye NH           N

      Bromoacrylamido                                     NF

                                             Difluorochloropyrimidine (DFCP)

Dye SO2CH2CH2OSO3Na                                           CH3
     Sulphatoethyl sulphone*   Dye SO2 CH2CH2 N CH2CH2SO3Na

                                       N-Methyltaurine ethyl sulphone*

                   (*give vinyl sulphone)

Figure 16.7 Types of reactive dyes for wool

                                         Br
                   Dye NH CO CH CH2 Br

                                         Br
                   Dye NH CO C CH2 + HBr

                      NH Wool                        Br
Dye NH CO C CH2                Dye NH CO CH CH2 NH Wool

                                                                    Wool
                                                                     N
                                          Dye NH CO CH CH2

                                                        NH Wool
                                  Dye NH CO CH CH2 NH Wool
Figure 16.8 Reactions of bromoacrylamido reactive dyes with wool

      Dye NHCOCH2Cl + Wool SH                Wool S CH2CONH Dye + HCl
Scheme 16.5
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