Page 29 - Electronic Configuration
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3)  Stability of the half-filled orbitals






          d block element can also donate electrons to

              achieve the stability of half-filled orbitals



              Example:


                                                                             2
                                                       6
                                         2
                                                              2
                                                2
                  Mn :             1s 2s 2p 3s 3p 4s 3d                             5
                                                                      6
                  Mn     2+            :      1s 2s 2p 3s 3p 3d                         5
                                                          2
                                                                         2
                                                                                6
                                                                  6
                                                   2
                         (stability of half-filled 3d orbital )

                                                                      6
                                                              2
                                         2
                                                                             2
                  Fe :             1s 2s 2p 3s 3p 4s 3d                             6
                                                       6
                                                2
                                                                      6
                                         2
                        3+
                  Fe :             1s 2s 2p 3s 3p 3d                         5
                                                       6
                                                              2
                                                2
                         (stability of half-filled 3d orbital)
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