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2.8     Matrices



                           In most engineering composite systems, matrices play vital roles in providing

                   unique characteristics for the composite. Composites used in certain industries such as

                   aerospace, is required to have minimum levels of thermal and electrical conductivity
                   and  the  designer  must  rely  on  the  matrix  properties.  Generally,  the  functions  and

                   requirements of the matrix are as follows [55];




                       •  Keeping the fibres in place in the structure
                       •  Help to distribute or transfer loads from external forces to the reinforcement.

                       •  Protect the filaments, both in the structure, before and during fabrication

                       •  Control the electrical and chemical properties of the composite
                       •  Carry inter-laminar shear




                           The matrix is often required in a finished composite as it provides a solid form

                   which aids its handling during manufacturing. The matrix also controls the infiltration
                   process that combines the fibres with the matrix as well during shaping and forming

                   of the composites. In addition, the matrix material provides a vital inelastic response
                   which reduces the stress concentrations dramatically. Furthermore, the presence of

                   matrix materials greatly influences the production cost for composites.






                   2.8.1  Thermoset




                           Thermoset is a polymeric material which can be formed by applying heat and

                   pressure. As a result of a chemical reaction, it is permanently cross linked and cannot
                   be reformed upon further application of heat and pressure [56]. Thermosetting resins

                   are often liquid at certain stages in their manufacturing process, they are then cured by
                   heat, catalysts, or other chemical means. The use of thermoset matrix for composite

                   material  properties  characterisation  has  garnered  attention  from  many  researchers

                   [11, 15, 21, 43, 47, 57–68]. Thermoset resins typically used in composites are epoxy,
                   phenolic,  unsaturated  polyester,  polyimides,  polyurethane  and  silicones.  The



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