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          tiL12214_appe_643-698.indd Page 677  09/10/10  8:37 AM user-f463              Volume/207/MHDQ243/tiL12214_disk1of1/0073512214/tiL12214_pagefile






                                                                                                                      −3
                                   _                m _                                                          5.7 × 10  g
                                   ρ mineral


                               SG =          and  ρ mineral  =       and  V = L × W × H                          __



                                    ρ water         V                                                               4 _ _
                                                                                                                         3
                                                                                                                   0.16 cm

                                                                                                                      π  (         )


                                                   __                                                          =    3 __
                                                                                                                     2
                                                       m



                                                                                                                     g
                                                   (L × W × H)
                                                   __                                                               _



                                            ∴ SG =                                                                 1
                                                                                                                      3
                                                      ρ water                                                       cm
                                                          25.09 g
                                                                                                                      −3
                                                   ___                                                           _
                                                                                                                 5.7 × 10




                                                                                                                          g
                                                   (2.89 cm)(1.86 cm)(1.79 cm)
                                                   ___                                                                π   (      ) 3 _
                                                                                                                 4 _
                                                                                                                    _
                                                                                                                    0.16







                                                 =                                                               3 _ cm   3
                                                                                                                     2
                                                                                                                        _
                                                            g
                                                           _


                                                          1                                                    =     1


                                                                                                                         g
                                                           cm 3                                                         _

                                                                                                                        cm 3
                                                                   g
                                                       25.09
                                                   __ __                                                              −3






                                                                                                                5.7 × 10

                                                   __ __                                                       =   _
                                                   (2.89)(1.86)(1.79) (cm)(cm)(cm)




                                                 =                                                               4 _  3
                                                                   g


                                                        1         _                                                   π0.08

                                                                                                                 3
                                                                  cm 3                                          _
                                                                                                                      −3
                                                                                                                5.7 × 10


                                                   25.09
                                                   _                                                          =       −3
                                                 =                                                              2.1 × 10
                                                   9.62
                                                 = 2.61                                                        = 2.7
                                                                                                          The feldspar grains will float.
                               Examination of Figure 17.11 shows sodium plagioclase
                               crystallizes at low temperature on Bowen’s reaction series.   17.5.   The bond type is determined from the electronegativity
                                                                                      difference between the elements in the mineral. Figure 9.10
                         17.3.   In this case, determine volume by using the formula for the   provides electronegativity values, and Table 9.5 explains the
                               volume of a sphere.                                    difference in absolute electronegativity in terms of the bond type.
                                 D = 3.2 cm                                           Moissanite
                                 m = 72.04 g                                             electronegativity of Si = 1.8
                                       g
                                      _                                                  electronegativity of C = 2.5
                               ρ water  = 1
                                      cm 3                                                      bond type = ?
                                 SG = ?                                                     difference = ∣2.5−1.8∣
                                   _                m _        4 _ _  )  3                          = 0.7
                                                                  D
                                   ρ mineral


                               SG =          and  ρ mineral  =       and  V =      π  (




                                    ρ water         V          3  2                          Moissanite has polar covalent bonds.
                                                         _
                                                            m
                                                            4 _  D _                  Fluorite


                                                              3


                                                              π   (       )              electronegativity of Ca = 1.0



                                                          3 _
                                                             2

                                                  ∴  SG =
                                                          ρ water                         electronegativity of F = 4.0
                                                           72.04 g
                                                         _                                      bond type = ?
                                                             3.2 cm                           difference = ∣4.0−1.0∣


                                                                 3
                                                          4 _ _

                                                              π  (    2      )

                                                          3 _
                                                       =      g                                       = 3.0

                                                             _
                                                           1                                 Fluorite has ionic bonds.

                                                             cm 3
                                                         _                            From Table 17.2, fluorite has a hardness of 4, so it is softer.
                                                           72.04
                                                            4 _  3.2 _    g


                                                               3 _
                                                              π   (     )                 17.6.   Use the silicon to oxygen ratio to determine the percent






                                                                  3
                                                                _
                                                             2



                                                       =    3 _ cm
                                                                 g
                                                            1   _                     composition. Determining percent composition is described in

                                                                 cm 3                 example 10.3.
                                                         _
                                                          72.04

                                                       =                        Olivine  Step 1:   Write the formula for a single tetrahedron based
                                                         4 _

                                                              π1.6 3

                                                         3                                 on ratio:  SiO 4
                                                         72.04
                                                         _                            Step 2:   Determine the formula weight of a single tetrahedron.
                                                       =
                                                          17
                                                                                            Atoms  Atomic  Weight   Total
                                                       = 4.2
                                                                                            1 of Si   1 × 28.09 u   =  28.09 u

                        17.4.   Determine the specific gravity of the mineral and compare it to   4 of O   4 × 16.00 u   =  64.00 u

                               the specific gravity of liquid bromoform.                          Formula weight  =  92.09 u
                                 D = 0.16 cm                                          Step 3:  Determine the percentage of silicon.
                                           −3
                                 m = 5.7 × 10  g                                            __        ×
                                                                                            (28.09 u Si)(1)


                                       g
                                      _                                                         92.09 u SiO 4    100%SiO 4     =    30.5% Si
                               ρ water  = 1
                                      cm 3                                     Hornblende
                                 SG = ?
                                                                                      Step 1:   Write the formula for a double chain based on
                                   _                m _        4 _ _  )  3
                                                                  D
                                   ρ mineral
                               SG =          and  ρ mineral  =       and  V =      π  (            ratio: Si 4 O 11






                                    ρ water         V          3  2
                                                                                      Step 2:   Determine the formula weight of a double chain.
                                                         _
                                                            m

                                                            4 _  D _

                                                              3



                                                              π   (       )                 Atoms  Atomic  Weight   Total


                                                          3 _
                                                             2

                                                  ∴  SG =                                   4 of Si   4 × 28.09 u   =  112.36 u
                                                          ρ water
                                                                                            11 of O   11 × 16.00 u   =  176.00 u
                                                                                                  Formula weight  =  288.36 u
                       E-35                                                       APPENDIX E  Solutions for Group A Parallel Exercises   677
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