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                          Step 3:  Determine the percentage of silicon.          of calcite. The formula is SG deposit  = SG galena (%galena) + SG calcite
                                (28.09 u Si)(4)
                                __        100%Si 4 O 11  =    39.0% Si           (%calcite).
                                          ×





                                288.09 u Si 4 O 11
                                                                            Step 1:   Percentage of Galena in Deposit
                          Hornblende has the higher percentage of silicon.
                                                                                  SG deposit  = 3.2
                    17.7.   Use the chemical formula to determine the percent     SG galena  = 7.5
                          composition as described in example 10.3.               SG calcite  = 2.7
                          Step 1:   Write the formula for galena:  PbS            %galena = ?
                          Step 2:   Determine the formula weight of galena.      SG deposit  = SG galena  (%galena) + SG calcite  (%calcite)
                                                                                 and: %calcite = 1 − %galena
                                Atoms  Atomic  Weight   Total
                                1 of Pb   1 × 207.2 u   =  207.2 u             ∴  SG deposit  = SG galena  (%galena) + SG calcite  (1 − %galena)
                                1 of S   1 × 32.07 u   =   32.07 u               SG deposit  = SG galena  (%galena) + SG calcite  − SG calcite  (%galena)
                                      Formula weight  =  239.27 u                 SG deposit  − SG calcite  = SG galena (%galena) + SG calcite  −
                                                                                                          SG calcite (%galena) − SG calcite
                          Step 3:  Determine the percentage of lead.
                                                                                  SG deposit  − SG calcite  = SG galena (%galena) − SG calcite (%galena)
                                __           100%PbS    =    86.6% Pb
                                (207.2 u Pb)(1)
                                          ×



                                 239.27 u PbS                                     SG deposit  − SG calcite  = (%galena)(SG galena  − SG calcite )
                    17.8.                                                                               (SG galena  − SG calcite )
                                                                                   __                   __
                                                                                   SG deposit  − SG calcite

                    Chalcopyrite                                                                  = (%galena)


                                                                                   SG galena  − SG calcite  (SG galena  − SG calcite )
                          Step 1:   Write the formula for chalcopyrite:  CuFeS 2
                                                                                                SG deposit  − SG calcite

                          Step 2:   Determine the formula weight of chalcopyrite.     ∴  %galena =    __       × 100

                                                                                                 SG galena  − SG calcite
                                Atoms      Atomic  Weight  Total                                _
                                                                                                 (3.2 − 2.7)

                                1 of Cu     1 × 63.55 u   =   63.55 u                          =    (7.5 − 2.7)     × 100
                                1 of Fe     1 × 55.85 u   =   55.85 u                           .05 _
                                2 of S      2 × 32.07 u   =   64.14 u                         =    4.8       × 100
                                           Formula weight  =  183.54 u                         = 10.4%
                          Step 3:  Determine the percentage of copper.           The second step is to determine the mass of the deposit. The
                                (63.55 u Cu)(1)
                                __           × 100%CuFeS 2   =    34.6% Cu       specific gravity is equal to the density of the deposit in either




                                                                                             3
                                                                                     3
                                183.54 u CuFeS 2                                 g/cm  or tonne/m . Use the density formula and solve for mass
                   Chalcocite                                                    in tonnes.
                          Step 1:   Write the formula for chalcocite:  Cu 2 S    Step 2:   Mass of Deposit
                          Step 2:   Determine the formula weight of chalcocite.  L = 500 m        m _

                                                                                               ρ =       and  V = L × W × H

                                                                                                  V
                                Atoms  Atomic  Weight   Total                  W = 100 m          __
                                                                                                      m

                                2 of Cu   2 × 63.55 u   =  127.10 u            H = 25 m        ρ =    (L × W × H)
                                                                                     tonne
                                1 of S   1 × 32.07 u   =   32.07 u              ρ = 3.2   _    ∴  m = ρ(L × W × H)




                                                                                                    tonne
                                      Formula weight  =  159.17 u                     m 3       = 3.2    _   (500 m × 100 m × 25 m)



                                                                               m = ?                 m 3
                          Step 3:  Determine the percentage of copper.                                           _     3
                                                                                                                 tonne

                                                                                                = 3.2(500 × 100 × 25)          (m )

                                __           100%Cu 2 S =    79.9% Cu                                             m 3
                                (63.55 u Cu)(2)
                                           ×



                                                                                                        6
                                159.17 u Cu 2 S                                                 = 4.0 × 10  tonnes
                          Chalcocite has the higher percentage of copper.        Then solve for the mass of galena based on its percentage.
                    17.9.   Determine the mass of galena in the deposit by multiplying the     Step 3:  Mass of Galena
                                                                                           6
                          total mass of the deposit by the ore grade.           m ore  = 4.0 × 10  tonnes  m galena  = m ore  (oregrade)
                                                                                                                6
                                                                             oregrade = 10.4% galena     = 4.0 × 10  tonnes(0.104)
                                    6
                        m ore  = 1.69 × 10  tonnes  m galena  = m ore  (ore grade)  m galena  = ?               5
                                                          6
                     ore grade = 8% galena        = 1.69 × 10  tonnes(0.08)                              = 4.2 × 10  tonnes
                                                          5
                       m galena  = ?              = 1.35 × 10  tonnes            Determine the mass of lead by multiplying the mass of galena by
                                                                                 the mass percentage of lead in galena (see exercise 17.7).
                          Determine the mass of lead by multiplying the mass of galena by
                          the mass percentage of lead in galena (see exercise 17.7).    Step 4:  Mass of Lead
                                                                                          5
                                    5
                       m galena  = 1.35 × 10  tonnes  m Pb  = m galena  (%Pb galena )      m galena  = 4.2 × 10  tonnes  m Pb  = m galena  (%Pb galena )
                                                                                                                5
                                                         5
                     % Pb galena  = 86.6%        = 1.35 × 10  tonnes(0.866)    % Pb galena  = 86.6%      = 4.2 × 10  tonnes(0.866)
                                                                               m Pb  = ?                        5
                         m Pb  = ?               =  1.17 × 10  tonnes                                    = 3.6 × 10  tonnes
                                                          5

                                                                           17.11.   Read the percentage associated with each mineral from
                    17.10.   Th e first step is to determine the percentage of galena in the ore


                                                                                 Figure 17.13, and calculate the difference to determine the
                          deposit. Since the average specific gravity of the deposit is a

                                                                                 percentage of each mineral.
                          function of the combined specific gravities of the minerals in the

                          deposit, the percentage of galena can be determined by a     Mixed amphibole-pyroxene: 100%−70%  =  30%
                          weighted sum calculation. In this case, the specific gravity of the     Mixed Na-Ca plagioclase:    70%−0%    =  70%


                          deposit equals the specific gravity of galena times the percentage

                          of galena plus the specific gravity of calcite times the percentage
                   678     APPENDIX E  Solutions for Group A Parallel Exercises                                         E-36
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