Page 51 - ACE YR IGCSE A TOP APPROACH TO CHEM
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12  C                                                 (ii)  Sodium is a very reactive metal.   [1]
                         Steel is used as the core of an overhead cable to prevent
                         sagging. This is because steel is strong. Aluminium is a       (e)  MgO + H O          [1]
                                                                                     2
                         better electrical conductor than steel.             CuO + CO                           [1]
                                                                                      2
                       13  C                                            3  (a)  Zn + 2HCl ➞ ZnCl  + H           [1]
                                                                                             2
                                                                                                 2
                         Rusting  can  be  prevented  by  stopping  oxygen  from       (b)  Lighted splint      [1]
                         reacting  with  iron.  Attaching  copper  to  the  shipʼs  hull          Pop sound     [1]
                         cannot prevent rusting because copper is less reactive
                         than iron. Iron will be reduced to form iron ion and react       (c)  No reaction      [1]
                         with oxygen.                                        Copper metal is unreactive. It cannot react with
                       14  A                                                 dilute hydrochloric acid.          [1]
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                         X can be zinc. Galvanising is a process of coating steel     4  (a)  (i)  Carbon is more reactive than zinc.   [1]
                         with zinc.
                         The metal used to coat steel should be more reactive.          (ii)  Blast / roast in oxygen to react with zinc
                         The  more  reactive  metal  will  lose  electrons  first.  The   sulfide.              [1]
                         metal is oxidised.                                      2ZnS + 3O  ➞ 2ZnO + 2SO 2
                                                                                        2
                                                                                 Carbon reacts with oxygen.     [1]
                     Part 2: Structured Questions                                C + O  ➞ CO
                                                                                     2    2
                       1  (a)  (i)  Z > X > Y > W              [1]               Carbon dioxide reacts with more carbon.
                            (ii)  Displacement reaction        [1]                                              [1]
                            (iii) Copper                       [1]               CO  + C ➞ 2CO
                                                                                   2
                                                                                 Zinc oxide is reduced by CO.   [1]
                         (b)  (i)  Sodium hydroxide + hydrogen   [1]             ZnO + CO ➞ Zn + CO
                                                                                                2
                            (ii)  2Li + 2HCl ➞ 2LiCl + H 2                       Calcium carbonate is added to neutralise
                                Correct formula for products   [1]               silicon dioxide.               [1]
                                Balanced equation              [1]               CaCO  + SiO  ➞ CaSiO  + CO
                                                                                     3   2       3   2
                            (iii)  2Mg + O  ➞ 2MgO                           (iii) Sulfur dioxide               [1]
                                       2
                                Correct formula for product    [1]               Carbon dioxide                 [1]
                                Balanced equation              [1]           (iv)  The temperature in the blast furnace is
                            (iv)  K  + Ag                      [2]               higher than the boiling point of zinc.  [1]
                                 +
                         (c)  (i)  Any two from:               [2]        (d)  (i)  Zinc is more reactive than iron.   [1]
                                •  Conduct electricity / heat                    Zinc loses electrons to form zinc ions.  [1]
                                •  Malleable / Ductile                           Zinc  ions  react  with  water  and  oxygen
                                •  Solid at room temperature                     instead of iron.               [1]
                            (ii)  Any three from:              [3]           (ii)  Sacrificial protection       [1]
                                •   Chromium   can   form   coloured             Magnesium blocks are also commonly used to
                                 compounds, but calcium does not.                protect steel ships.
                                •   Chromium  has  catalytic  activity,  but       (e)  Any one from:           [1]
                                 calcium does not.                           •  Coins
                                •   Chromium has variable oxidation states,          •  Musical instruments
                                 but calcium does not.                       •  Doorknobs
                                •   Chromium can form complex ions, but          •  Ornaments
                                 calcium does not.
                                •   Chromium is less reactive than calcium.      (f)  Atoms are of different sizes.   [1]
                            (iii) Add sodium hydroxide.        [1]           The layers of atoms cannot slide over each other
                                Chromium  turned  into  a grey-green         easily.                            [1]
                                precipitate. Calcium turned into a white     5  (a)  Any one from:
                                precipitate.                   [1]           Use: Overhead cable                [1]
                       2  (a)  Lead(II) oxide                  [1]           Property:  Good  conductor  of  electricity  /
                            Nitrogen oxide                     [1]           Ductile                            [1]
                                                                             Or
                         (b)  2Pb(NO )  ➞ 2PbO + 4NO  + O 2                  Use: Cooking foil                  [1]
                                                  2
                                   3 2
                            Correct formula for products       [1]           Property: Resistant to corrosion   [1]
                            Balanced equation                  [1]           Or
                         (c)  Thermal decomposition            [1]           Use: Drinks cans                   [1]
                                                                             Property: Resistant to corrosion / Light   [1]
                         (d)  (i)  Sodium nitrite + oxygen     [2]



                                                                                                     Answers    163







         Answers.indd   163                                                                                         3/4/22   3:54 PM
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