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3                    The Mole Concept, Chemical
              Chapter                                    Formula and Equation





             NOTES


              3.1   Relative Atomic Mass and                     2.   Avogadro constant, N  is defined as the number of
                                                                                      A
                    Relative Molecular Mass                        particles in one mole of a substance. In other words,
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                                                                   1 mol of substance contains 6.02 × 10  particles that
                                                                                                  23
               1.  The mass of an atom when compared to a standard   form the substance.
                 atom is called relative atomic mass, RAM. Relative     3.  When we say, 2 pairs of shoes, it means 2 × 2 = 4
                 atomic mass has no unit because it is not the actual   shoes. If we were to say 2 dozen of shoes, that means
                 mass but only a comparison value.                 2 × 12 = 24 shoes.
                                                                 4.  What if we say 2 moles of shoes? It means 2 × 6.02 ×
                  Standard atom        Why is it chosen            10  = 1.204 × 10  shoes.
                                                                     23
                                                                                 23
                  Carbon-12      •  Carbon-12 was used as the             × N
                  The mass of one   reference standard in mass               A
                  carbon-12 atom   spectrometers.                             Number of
                  was assigned   •  Most elements combine with   Number of     particles  Number of moles, n
                  12 units.        carbon-12.                    moles, n      Atom //    =    Number of particles
                                 •  Exists as a solid at room                 molecule //          N A
                                   temperature and easy                          ion
                                   to handle.                             ÷ N
                                                                             A
               2.  Based on the carbon-12 scale,  the  relative  atomic     5.  The  molar mass is the  mass of one mole of the
                 mass of an element is the average mass of one atom   substance.
                                                1                                                           23
                 of the element when compared with  12  of the mass     6.  The molar mass of a substance contains 6.02 × 10
                 of one carbon-12 atom.                            particles of the substance.
                                                                 7.  The unit of molar mass is g mol .
                                                                                             –1
                    Relative atomic mass (RAM)
                     Average mass of one atom of the element           × molar mass
                  =     1                                                                 Number of moles, n
                           × Mass of one carbon – 12 atom        Number of
                        12                                                         Mass        Mass
                                                                 moles, n                 =    Molar mass
               3.   Relative molecular mass of a molecule is defined as   ÷ molar mass
                 the average mass of the molecule when compared
                      1
                 with    of the mass of one carbon-12 atom.      8.  The molar volume of a gas is the volume occupied
                     12                                            by one mole of the gas or  6.02  × 10  particles
                                                                                                    23
                    Relative molecular mass (RMM)                  of the gas.
                                                                                                 –1
                                                                                             3
                       Average mass of one molecule              9.  The unit of molar volume is dm  mol .
                  =   1                                         10.  Under the same temperature and pressure, an equal
                        × Mass of one carbon – 12 atom             number of moles of any gas will have  the  same
                     12
                                                                   volume.
               4.  The term ‘relative molecular mass’ can only be used    11.  The molar volume depends on the conditions.
                 for substances that are made up of molecules.
                 For  ionic compounds, the ‘relative  formula  mass             Molar volume
                 (RFM) is used instead.                         Standard temperature and   Room conditions:
                                                                pressure, STP:         Temperature = 25 °C
              3.2   Mole Concept                                Temperature = 0 °C     Pressure =1 atm
               1.  One mole, with  the  symbol ‘mol’ of substance  is   Pressure = 1 atm
                 defined as:                                         22.4 dm  mol –1         24 dm  mol –1
                                                                                                  3
                                                                           3
                  Substance that contains 6.02214076 × 10 23        22400 cm  mol –1       24 000 cm  mol –1
                                                                                                   3
                                                                            3
                  elementary entities of the substance.

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