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Science SPM  Chapter 6 Electrochemistry

                   6.1    Electrolytic Cell


               Electrolysis
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                1.  Electrolysis  is the  decomposition of a  compound in the  molten or aqueous
                    state  into its constituent  elements when electric  current  flows  through  it.
                2.  Electrolysis occurs in an electrolytic cell. The figure below shows the structure
                    of an electrolytic cell.


                                                BATTERIES           Battery as a source
                                                                    of electrical energy
                                                     +    –
                             Anode                                       Cathode
                    Electrode that is connected to the           Electrode that is connected to the
                     positive terminal of the batteries          negative terminal of the batteries



                              Anion
                      Negatively-charged particles     –
                                                     –  +
                             Electrolyte                –                 Beaker
                     Molten compound or aqueous      +
         Form 5
                      solution which contains free                        Cation
                            moving ions                +           Positively-charged particles

                                             Figure 6.1 Electrolysis

                  SPM TIPS                                    SPM TIPS

                  An electrode is an electric conductor (metal   A solid  ionic compound  is not an
                  plate or carbon rod) that is dipped into an   electrolyte because its ions cannot
                  electrolyte and carries electric current into   move freely.
                  or out from the electrolyte.

                4.  Processes that take place at the         (b)  In  the connecting  wire
                    anode and the cathode of the                •  The electrons released by anions
                    electrolytic cell when an electric            flow to the cathode through the
                    current  is passed through it:                connecting wire.
                    (a)  At the anode                        (c)  At  the cathode
                       •  Anions (negatively-charged            •  Cations  (positively-charged
                         particles)  move  toward  the            particles)  move  toward  the
                         anode.                                   cathode.
                       •  Anions release electrons at           •  Cations receive  electrons at
                         the  anode to form atoms  or             the cathode to form atoms or
                         molecules.                               molecules.
                       •  Anions are discharged at the           •  Cations  are  discharged  at
                         anode.                                   the  cathode.


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