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Science SPM  Chapter 6 Electrochemistry
               Applications  of Electrolysis  in Industries
                A   Extraction of metals
                1.  Metals  such  as  potassium,  sodium,  calcium,  magnesium  and  aluminium  are  more
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                    reactive  than  carbon,  hence  these  metals  cannot  be  extracted  by  heating  with
                    carbon.
                2.  Metals  such  as  potassium,  sodium,  calcium,  magnesium  and  aluminium  must  be
                    extracted using electrolysis.
                3.  The figure below shows the process of extracting  aluminium  using electrolysis.


                             Anode                   +  Carbon electrodes
                  •  Oxide ions move toward the      –                       Insulator
                    anode.
                  •  Oxide ions release electrons   Carbon                   Molten aluminium
                    and form oxygen gas.                                     oxide in cryolite
                  •  Oxide ion ➞ oxygen + electrons                          Molten aluminium



                                                                   Cathode
         Form 5
                                                   •  Aluminium ions move toward the cathode
                                                   •  Aluminium ions receive electrons and form
                                                     molten aluminium
                                                   •  Aluminium ion + electrons ➞ aluminium
                                   Figure 6.7 Extraction of aluminium by electrolysis

                B   Electroplating  of  metals
                                                                              Cathode
                                                                      •  Copper(II) ions and
                                                                        hydrogen ions move
                                                                        toward the cathode.
                        Anode
                                                                      •  The copper(II) ion is
                •  Copper dissolves to           +      –               selected to be discharged
                  produce copper(II)                                    because its position
                  ions                                                  in the electrochemical
                •  Copper ➞ copper(II)   Copper             Key         series is lower.
                  ion + electrons       (Anode)             (Cathode)  •  A thin layer of copper
                                                                        metal is plated onto the
                                            Copper(II) sulphate solution  metallic object (iron key)
                                                                        which acts as cathode.
                                                                      •  Copper(II) ions + electrons
                                                                        ➞ copper atoms
                                             Figure 6.8 Electroplating




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