Page 20 - Ranger SPM 2022 Chemistry
P. 20

Chemistry SPM  Chapter 2  Carbon Compound
                   5.  Structural  formulae and IUPAC nomenclature for alcohols:

                                 H                      H H                    H H H
                                 &                      & &                    & & &
                              H!C!OH                 H!C!C!OH               H!C!C!C!OH
             Penerbitan Pelangi Sdn Bhd. All Rights Reserved.
                                 &                      & &                    & & &
                                 H                      H H                    H H H
                               Methanol                 Ethanol                Propan-1-ol
                               (CH OH)                 (C H OH)                (C H OH)
                                  3                      2  5                    3  7
                             H H H  H               H H H  H H             H H H  H H  H
                             & & &  &               & & &  & &             & & &  & &  &
                          H!C!C!C!C!OH           H!C!C!C!C!C!OH         H!C!C!C!C!C!C!OH
                             & & &  &               & & &  & &             & & &  & &  &
                             H H H  H               H H H  H H             H H H  H H  H
                              Butan-1-ol              Pentan-1-ol              Hexan-1-ol
                               (C H OH)                (C H OH)                (C H OH)
                                4  9                     5  11                   6  13
                   6.  Structural  formulae and IUPAC nomenclature for carboxylic acids:

                                 O                      H O                    H  H O
                                 '                      &  '                   &  &  '
                              H!C!OH                 H!C!C!OH               H!C!C!C!OH
                                                        &                      &  &
                            Methanoic acid              H                      H H
                               (HCOOH)
                                                 Ethanoic acid (CH COOH)  Propanoic acid (C H COOH)
                                                               3                      2  5
                             H  H  H O              H  H  H H  O           H  H  H H  H O
                             &  &  &  '             &  &  &  &  '          &  &  &  &  &  '
                          H!C!C!C!C!OH           H!C!C!C!C!C!OH         H!C!C!C!C!C!C!OH
                             &  &  &                &  &  &  &             &  &  &  &  &
                             H H  H                 H  H  H H              H  H  H H  H
                        Butanoic acid (C H COOH)  Pentanoic acid (C H COOH)  Hexanoic acid (C H COOH)
                                     3  7                     4  9                    5  11
                   7.  Physical  properties  of  alkanes,           –  molecular size increases.
                      alkenes and  alkynes                          –  van  der  Waals  attraction
                      •  Members  of  alkane,  alkene  and             force between  molecules
                        alkyne  homologous  series are                 becomes stronger.              Form 5
                        neutral molecules.                          –  more heat energy is needed
                      •  Have low melting point and boiling            to overcome the van  der
                        point                                          Waals attraction  force.
                      •  Odourless                               (b)  Viscosity  of    molecules
                      •  Less dense than water                      increases.
                      •  Soluble in  organic solvents            (c)  Density of molecules increases.
                      •  Insoluble in  water                     (d)  Molecules  become     less
                      •  Cannot  conduct  electricity  in  any      flammable.
                        state                               8.  Physical properties of alcohols
                      •  When the number of carbon atoms       •  Alcohols   are   non-hydrocarbon
                        per molecule increases,                  organic  compounds   containing
                        (a) Melting point and boiling point      carbon, hydrogen and oxygen
                           will increase because                 atoms.


                                                       149





         02.5 RANGER SPM CHEMISTRY 2P.indd   149                                            29/03/2022   2:28 PM
   15   16   17   18   19   20   21   22   23   24   25