Page 26 - Ranger SPM 2022 Chemistry
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Chemistry SPM  Chapter 2  Carbon Compound
                     Tabulation of data:
                                                               Observation
                    Set        Test
                                                  Hexane                     Hexene
                         = 85.7 %Pelangi Sdn Bhd. All Rights Reserved.
                     A   Reaction with    •  Burns with yellow flame.  •  Burns with bright yellow flame.
                         oxygen gas       •  A little soot is formed on   •  More soot is formed on the
                                            the filter paper.       filter paper.
                     B   Reaction with    •  Brown colour of bromine   •  Brown colour of bromine
                         bromine water      water remains brown.    water turns colourless.
                     C   Reaction with    •  Purple colour of      •  Purple colour of acidified
                         acidified potassium   acidified potassium   potassium manganate(VII)
                         manganate(VII)     manganate(VII) solution   solution turns colourless.
                         solution           remains purple.

                     Discussion:                             4.  Hexane  does  not  react  with  both
                     1.  Hexene which is an example of alkene   bromine  water  and  acidified  potassium
                      burns  with  more  soot  compared  to   manganate (VII) solution because it is a
                      hexane which is an example of alkane    saturated hydrocarbon.
                      of  the  same  number  of  carbon  atoms     5.  Hexene reacts with both bromine water
                      per molecule.                           and acidified potassium manganate(VII)
                     2.  Chemical  equation  for  the  combustion   solution  because  it  is  an  unsaturated
                      of both hexane and hexene:              hydrocarbon.
                        •  2C H (l) + 19O (g) →                 •  C H (l) + Br (aq) → C H Br (l)
                            6  14     2                           6  12    2       6  12  2
                                      12CO (g) + 14H O(l)       •  C H (l) + H O(g) + 2[O] →
                                                                          2
                                                   2
                                                                    12
                                                                  6
                                          2
                        •  C H (l) + 9O (g) →                                       C H (OH) (l)
                           6  12    2                                                6  12  2
                                        6CO (g) + 6H O(l)
                                                   2
                                           2
                     3.  Percentage  of  carbon  in  both  hexane    Conclusion:
                      and hexene:                            1.  Both  hexane  and  hexene  undergo
                        (a) Percentage of carbon in hexane    combustion.
                              6(12)                          2.  Hexene  produces  more  soot  than
                          =            × 100%                 hexane.
                           6(12) + 14(1)
                           = 83.7 %                          3.  Hexane  does  not  react  with  both
                                                              bromine  water  and  acidified  potassium
                        (b) Percentage of carbon in hexene    manganate(VII) solution.
                              6(12)    × 100%                4.  Hexene reacts with both bromine water   Form 5
                         =


             Penerbitan
                           6(12) + 12(1)
                                                              and acidified potassium manganate(VII)


                                                              solution.
                    SPM TIP
                     •  Alkane is a cleaner fuel compared to alkene because alkane has a lower percentage of
                       carbon.
                     •  Alkane  and  alkene  can  be  easily  differentiated  by  using  a  few  drops  of  brown  bromine
                       water.
                     •  The colour change of bromine water is very effective to identify the presence of carbon-
                       carbon double bond or carbon-carbon triple bond.
                                                       155





         02.5 RANGER SPM CHEMISTRY 2P.indd   155                                            29/03/2022   2:28 PM
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