Page 27 - Ranger SPM 2022 Chemistry
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Chemistry SPM  Chapter 2  Carbon Compound
               Alcohol
                1.  Preparation of alcohol through two chemical reactions:
                    (a)  Fermentation
                       •   Carbohydrate  which  is sugar  or starch  undergoes fermentation  in the
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                           absence  of oxygen  by  using a  catalyst  called  zymase  enzyme  (yeast)  to
                           produce ethanol and carbon  dioxide.
                       •   C H O (aq)   Zymase enzyme   2C H OH(l)  + 2CO (g)
                            6
                                                      2
                                                        5
                                 6
                              12
                                                                    2
                       •   Fractional distillation is carried out to produce pure ethanol.
                                                                      Thermometer
                                                                         Water out
                                                                               Liebig
                                                   Fractionating               condenser
                                                   column              Filtered
                                                                       fermentation
                                                                       product
                                                   Water                  Water in

                          Glucose Limewater                              Ethanol,
                          solution                                Heat   C H OH
                                                                           2
                                                                            5
                           + yeast
                  (a) Set up of apparatus for fermentation   (b) Set up of apparatus for distillation
                                                 Diagram 2.8
                   Type of     Apparatus                      Observation
                 carbohydrate    set-up
                     Rice                 •  Colourless bubbles are observed in the fermentation solution.
                                  (a)
                                          •  Colourless bubbles turn limewater cloudy.
                                  (b)     •  The distillate is a colourless liquid and has a sharp smell.
                 Pineapple juice          •  Colourless bubbles are observed in the fermentation solution.
                                  (a)
                                          •  Colourless bubbles turn limewater cloudy.
                                  (b)     •  Distillate formed is a colourless liquid and has a sharp smell.

                       •   Equation     for      the                organic molecules  to simple
                           fermentation  of rice and                compounds.
         Form 5
                           pineapple juice:                     •   The  mixture  solution  must
                           C H O (l) → 2C H OH(l)                   be placed in a closed conical
                            6
                                            5
                                 6
                              12
                                         2
                                           +  2CO (g)               flask  because  fermentation
                                                 2
                       •   Glucose  fermentation  will              is an anaerobic process.
                           produce ethanol and carbon           •   Presence  of  oxygen  during
                           dioxide.                                 fermentation      oxidises
                       •   Yeast  is  added  into  rice             ethanol to ethanoic acid.
                           and pineapple  solution to           •   Enzyme zymase denatures at
                           produce   zymase  enzyme                 the end of the fermentation
                           that can  convert  complex               when the  percentage of
                                                                    ethanol increases to 14%.
                                                    156





         02.5 RANGER SPM CHEMISTRY 2P.indd   156                                            29/03/2022   2:28 PM
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