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MODULE • Chemistry Form 4


                EXERCISE / LATIHAN

                      3
                                  –3
             1   50 cm  of 2 mol dm  sulphuric acid is added to an excess of copper(II) oxide powder. Calculate the mass of copper(II)
                 sulphate formed in the reaction. [Relative atomic mass: H = 1, O = 16, Cu = 64, S = 32]
                 50 cm  asid sulfurik 2 mol dm  ditambah kepada serbuk kuprum(II) oksida berlebihan. Hitungkan jisim kuprum(II) sulfat yang terbentuk
                     3
                                       –3
                 dalam tindak balas itu. [Jisim atom relatif: H = 1, O = 16, Cu = 64, S = 32]
                 M   = 2 mol dm –3
                 V   = 50 cm               ?   g
                          3
                 CuO(aq) + H SO (aq)    CuSO (ak) + 2H O(l)
                            2  4            4        2
                                                 2 × 50
                 Number of moles of sulpuric acid =      = 0.1 mol
                                                 1 000
                   From the equation,   1 mol CuO : 1 mol CuSO
                                                        4
                                   0.1 mol CuO : 0.1 mol CuSO 4
                 Mass of CuSO  = 0.1 mol × [64 + 32 + (16 × 4)] g mol  = 16 g
                                                                 –1
                            4
             2   27.66 g of lead(II) iodide is precipitated when 2.0 mol dm  of aqueous lead(II) nitrate solution is added to an excess
                                                                   –3
                 of aqueous potassium iodide solution. Calculate the volume of aqueous lead(II) nitrate solution used. [Relative atomic
                 mass: I = 127, Pb = 207]
                                                            –3
                 27.66 g plumbum(II) iodida termendak apabila 2.0 mol dm  larutan plumbum(II) nitrat akueus ditambahkan kepada larutan kalium iodida
                 akueus berlebihan. Hitungkan isi padu plumbum(II) nitrat yang digunakan. [Jisim atom relatif: I = 127, Pb = 207]
                 M   = 2 mol dm
                             –3
                 V   = ? cm                25 g
                         3
                  Pb(NO ) (aq) + 2KI(aq)    PbI (s) + 2KNO (aq)
                       3 2                   2         3
                                  27.66
                 Mol of PbI  =               = 0.06 mol
                         2   (207 + 2 × 127)
                 From the equation,     1   mol PbI  : 1 mol Pb(NO )
                                              2            3 2
                                   0.06 mol PbI  : 0.06 mol Pb(NO )
                                              2               3 2
                                       n mol        0.06 mol
                 Volume of Pb(NO )  =   M mol dm –3   =   2 mol dm –3   = 0.03 dm  = 30 cm 3
                                                                       3
                               3 2

                                                 3
                                                            –3
             3   Zinc oxide powder is added to 100 cm  of 2 mol dm  nitric acid to form zinc nitrate. Calculate
                 Serbuk zink oksida ditambahkan kepada 100 cm  asid nitrik 2 mol dm  untuk membentuk zink nitrat. Hitungkan
                                                                   –3
                                                    3
                 (i)  the mass of zinc oxide that has reacted.
                     jisim zink oksida yang bertindak balas.
                 (ii)  the mass of zinc nitrate produced. [Relative atomic mass: H = 1, O = 16, Cl = 35.5, Zn = 65]
                     jisim zink nitrat yang terhasil. [Jisim atom relatif: H = 1, O = 16, Cl = 35.5, Zn = 65]
                 (i)  2HNO (aq) + ZnO(s)    Zn(NO ) (aq) + H O(l)
                          3                      3 2      2
                                              100 × 2
                     Number of moles of HNO  =         = 0.2 mol
                                          3    1 000
                     From the equation,  2 mol of HNO  : 1 mol of ZnO
                                                  3
                                     0.2 mol of HNO  : 0.1 mol of ZnO
                                                  3
                     Mass of ZnO = 0.1 × [65 + 16] = 8.1 g
                 (ii)  From the equation,  2 mol of HNO  : 1 mol of Zn(NO )
                                                   3              3 2
                                     0.2 mol of HNO  : 0.1 mol of Zn(NO )
                                                   3                3 2
                                                                           –1
                     Mass of Zn(NO )  = 0.1 mol × [65 +[14 + (16 × 3)] × 2] g mol  = 0.1 × 189 = 18.9 g
                                 3 2








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        07-Chem F4 (3p).indd   152                                                                                 12/9/2011   5:55:22 PM
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