Page 8 - 1202 Question Bank Chemistry Form 5 KSSM
P. 8

•  A  protective  surface  prevents  water  and
                                             Rust (Fe O .xH O)
                Drop of water                      2  3  2                air  from  coming  into  contact  with  the  iron.
                                                                          Example:  paint,  grease,  oil,  plastic,  metals
                                                                          and using other metals.
                                                OH −                    •  Example of using other metals: Galvanisation
                    O                                 O 2
                     2                                                    involves coating iron with a layer of zinc. Tin
                                  Fe 2+                                   plating or tinning is a process of coating iron
                                        e −
                                                                          with a thin layer of tin. Chrome plating is used
                                                                          on car bumpers and decorative items.
                           Anode (–)       Cathode (+)              (b)  Alloying
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                                  2+
                           Fe(s)    Fe (aq) + 2e −  O (g) + 2H O(l) + 4e  −
                                            2      2                    •  Alloy  such  as  stainless  steel  is  made  of  a
                                                 −
                                                4OH (aq)
                 Iron metal                                               mixture  of  iron  with  chromium  and  nickel.
                                                                          This  alloy  has  a  very  high  resistance  to
                2.  Corroded iron is covered with a layer of red-brown    corrosion.  Chromium  and  nickel  form  oxide
                  compound.  The  red-brown  compound  is  hydrated       layer that is very strong and impermeable to
                  iron(III) oxide, Fe O .xH O or rust.
                                 2  3  2                                  air and water.
                3.  Corroded  copper  is  covered  with  a  green  layer.   (c)  Sacrificial protection
                  The green compound is basic copper(II) carbonate,     •  Involves placing a more electropositive metal
                  CuCO .
                       3                                                  in contact with iron.
                4.  Ways to prevent rusting:                            •  Example:  Magnesium  acts  as  a  sacrificial
                  (a)  Use a protective surface                           metal to protect underground iron pipes from
                                                                          rusting.

                                                         PAPER 1


              Each question is followed by four options A, B, C or D . Choose the best option for each question.


               1.1   Oxidation and Reduction                      4.  Carbon  is  a  non-metal  and  it  can  be  used  to
                                                               SPM  reduce metal oxides. In the reactivity series of
                                                               SPM
                                                               CLONE
                                                                    metals, carbon is located between
                1.  Ethanol  is  the  second  member  of  the  alcohol
             SPM
             SPM  family. Ethanol reacts with acidified potassium   A  calcium and aluminium
              CLONE                                                 B  aluminium and zinc
                  dichromate(VI) to form ethanoic acid. What type   C  zinc and iron
                  of reaction is involved in this conversion?       D  iron and lead
                  A  Esterification     C  Halogenation
                  B  Dehydration        D  Oxidation
                                                                  5.  Diagram 1 shows the experimental set-up used
                                                               SPM
                                                               SPM  to investigate a redox reaction. During a redox
                2.  Oxidising agent is used to oxidise iron(II) sulphate   CLONE
             SPM
             SPM  to iron(III) sulphate. Which of the following is   reaction, transfer of electron at a distance takes
              CLONE                                                 place between the oxidising agent and reducing
                  not an oxidising agent for the reaction?          agent which were separated by solution X.
                  A  Chlorine
                  B  Potassium bromide                                                G
                  C  Hydrogen peroxide
                  D  Concentrated nitric acid                                  Graphite electrodes  HOTS Analysing
                                                                                 –         +
                3.  What  is  the  oxidation  number  of  hydrogen  in
             SPM
             SPM  aluminium hydride, AlH ?                            Potassium                Potassium
              CLONE                     3                               iodide                 manganate
                  A  −1                 C  +1                          solution                (VII) solution
                  B  0                  D  +2                         Solution X

              4    Question 4:                                  Question 5:        Diagram 1
                SOS TIP  Refer to the positions of metals in the reactivity series of metals.  Reduction half-equation:  2+  2
                   You need to memorise this series.
                                                                MnO  + 8H  + 5e  → Mn  + 4H O
                                                                           −
                                                                       +
                                                                    −
                                                                   4
                                                                H  ions are supplied by aqueous acid solution
                                                                 +
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