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12  (a)  Zn(s) + CuCl (aq) ➞ ZnCl (aq) + Cu(s)    5  A
                                    2          2
                                                                       Aluminium oxide is an amphoteric oxide. An amphoteric
                                                                       oxide can act as both an alkali and an acid. Therefore, it



                          0     +2 –1      +2 –1      0                neutralises both the acid and base.
                         1 mark if all oxidation numbers of reactants are     6  B  2+         –

                                                                       Lead ion (Pb ) and iodide ion (I ) are needed to form
                         correct.                            [1]       lead iodide.
                         1 mark if all oxidation numbers of products are
                         correct.                            [1]     7  C
                                                                       Sulfur dioxide is acidic. It cannot neutralise acids.
                      (b)  Yes                               [1]       Zinc  oxide  is  an  amphoteric  oxide.  It  neutralises  both
                         The oxidation number of Zn changes from 0 to   acids and bases.
                         +2.                                 [1]       Iron(III) oxide is alkaline. It neutralises acids.
                         It  is  an  oxidation  as  the  oxidation  number      Carbon monoxide is a neutral oxide. It has pH 7.
                         increases.                          [1]     8  D
                         The oxidation number of Cu changes from +2                     pH 1     pH 7    pH 14
                         to 0.                               [1]
                         It  is  a  reduction  as  the  oxidation  number   Universal   Pink / red  Green  Blue /
                         decreases.                          [1]        indicator                        purple
                                                                        Methyl orange   Red     Orange   Yellow
                      (c)  Zn(s) + Cu (aq) ➞ Zn (aq) + Cu(s)   [1]
                                            2+
                                  2+
                         When writing an ionic equation, spectator ions are   Phenolphthalein Colourless Colourless   Pink
                         not needed.
                                                                     9  D
                      (d)  It is not a redox reaction.       [1]       Fe   reacts  with  ammonia  to  form  a  red-brown
                                                                         3+
                         All  ions  do  not  show  change  in  oxidation   precipitate.
                                                                        –
                         number.                             [1]       Cl  reacts with silver nitrate to form silver chloride which
                                                                       is a white precipitate.
                                                                       Water droplets are formed due to the condensation of
                    7    Acids, Bases and Salts                        water. It means the compound is hydrated.
                                                                     10  B
                  Part 1: Multiple-choice Questions                    Copper is less reactive than hydrogen. It cannot react
                                                                       with dilute acid. However, copper compounds such as
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                      Metal  oxide  is  basic.  So,  copper(II)  oxide  is  basic.  The   copper(II)  oxide  and  copper(II)  carbonate  react  with
                      reaction  between  copper(II)  oxide  and  dilute  sulfuric   dilute sulfuric acid.
                      acid  is  a  neutralisation  reaction.  Before  copper(II)      Zinc,  zinc  oxide  and  zinc  carbonate  react  with  dilute
                      oxide  is  added,  there  is  dilute  sulfuric  acid  in  the   sulfuric acid.
                      beaker. Therefore, the pH is less than 7. Since this is a
                      neutralisation  reaction,  the  salt  solution  obtained  is   Part 2: Structured Questions
                      neutral, which is pH 7.                        1  (a)  (i)  Aluminium oxide            [1]
                    2  B                                                  (ii)  Carbon monoxide              [1]
                      When dilute sulfuric acid reacts with barium compound,          (iii) Calcium oxide    [1]
                      a white precipitate is obtained. The white precipitate is
                      barium sulfate.                                     (iv)  silicon dioxide              [1]
                      Ba (aq) + SO (aq) ➞ BaSO (s)                        (v)  Iron(III) oxide               [1]
                        2+
                                2–
                               4
                                          4
                      When  dilute  sulfuric  acid  reacts  with  carbonate
                      compound,  carbon  dioxide  is  produced.  Bubbles  are          (vi) Sulfur dioxide   [1]
                      seen.                                               (vii) Carbon dioxide               [1]
                      Cu ,  Zn ,  NH   react  with  SO   will  form  aqueous
                                              2–
                        2+
                                 +
                            2+
                                              4
                                 4
                      solutions.                                       (b)  Add acid                         [1]
                      Dilute  sulfuric  acid  does  not  react  with  chloride          and alkali (suggest an acid and an alkali)   [1]
                      compound.                                           Both give reactions.               [1]
                    3  D                                               (c)  Iron(III) oxide is a base.       [1]
                      Magnesium oxide reacts with dilute acid to form a salt     2  (a)  Proton donor / H  donor   [1]
                                                                                        +
                      and water.
                      Copper does not react with dilute acid.          (b)  H SO  ➞ H  + HSO                 [1]
                                                                                    +
                                                                                           –
                      Calcium carbonate reacts with dilute acid to form a salt   2  4     4
                                                                                                   –
                                                                                        +
                      and carbon dioxide.                              (c)  CH COOH L H  + CH COO            [1]
                                                                             3
                                                                                              3
                    4  B                                               (d)  A strong acid is ionised completely in water. [1]
                      A base can be neutralised by an acid to form a salt. It will          A weak acid is ionised partially in water.   [1]
                      turn a damp red litmus paper blue.
                        Cambridge IGCSE  TM
                  156     Ace Your Chemistry

         Answers.indd   156                                                                                         3/4/22   3:54 PM
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